Faculty Publications
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Item Large scale synthesis of carbon nanofibres on sodium chloride support(InTech Europe info@sagepub.co.uk, 2012) Rajarao, R.; Badekai Ramachandra, B.R.Large scale synthesis of carbon nanofibres (CNFs) on a sodium chloride support has been achieved. CNFs have been synthesized using metal oxalate (Ni, Co and Fe) as catalyst precursors at 680 °C by chemical vapour deposition method. Upon pyrolysis, this catalyst precursors yield catalyst nanoparticles directly. The sodium chloride was used as a catalyst support, it was chosen because of its non-toxic and water soluble nature. Problems, such as the detrimental effect of CNFs, the detrimental effects on the environment and even cost, have been avoided by using a water soluble support. The structure of products was characterized by scanning electron microscopy, transmission electron microscopy and Raman spectroscopy. The purity of the grown products and purified products were determined by the thermal analysis and X-ray diffraction method. Here we report the 7600, 7000 and 6500 wt% yield of CNFs synthesized over nickel, cobalt and iron oxalate. The long, curved and worm shaped CNFs were obtained on Ni, Co and Fe catalysts respectively. The lengthy process of calcination and reduction for the preparation of catalysts is avoided in this method. This synthesis route is simple and economical, hence, it can be used for CNF synthesis in industries. © 2012 Rajarao and Bhat.Item RGO supported Co-Ni bimetallic magnetically separable nanocatalysts for the reduction of 4-Nitrophenol(Elsevier Ltd, 2016) Prasad, R.; Lolakshi, M.K.; Badekai Ramachandra, B.R.The Cobalt-Nickel-reduced graphene oxide ternary composite was prepared using eco-friendly, solvent-free and low temperature CVD method where in metal formates were used as metal precursor. The structure, composition and morphology of synthesized samples were characterized by several related techniques like X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The catalytic efficiency towards reduction of an organic pollutant such as 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) was explored and the reaction parameters like temperature, weight ratio of the composite was optimised and rate constant of the reactions were measured. The results show 8% Co-Ni-rGO are having high catalytic efficiency and can complete the reduction reaction within 250 s at 45 °C. Furthermore, catalyst being magnetically separable shows high stability after ten successive reactions. Hence, the Co-Ni-rGO composite can be a potential promising material to catalyse the reduction of 4-NP. © 2016 Elsevier B.V. All rights reserved.Item Microstructural characterization of low temperature plasma-nitrided 316L stainless steel surface with prior severe shot peening(Elsevier Ltd, 2016) Jayalakshmi, M.; Huilgol, P.; Badekai Ramachandra, B.R.; Bhat, K.U.Surface nanocrystallization by severe deformation has proven beneficial as pre-treatment to plasma nitriding. It aids in achieving thicker nitride layers at lower temperatures thus making the process more economical. In austenitic stainless steels, severe deformation leads to formation of strain induced martensite on the surface while plasma nitriding alone forms expanded austenite. However, structural characteristics of surface layer of pre-deformed steel after plasma nitriding is still a matter of debate. In present study, 316L stainless steel was subjected to severe shot peening: followed by plasma nitriding at 400 °C for 4 h. Characteristics of sample surface before and after treatment were analyzed by scanning electron microscopy, X-ray diffractometry and transmission electron microscopy techniques. Results showed that, this duplex treatment leads to formation of about 45 ?m thick nitride layer; without CrN precipitation. This is significantly high compared to reported data considering the temperature and duration of nitriding treatment employed. Selected area electron diffraction pattern from topmost surface confirmed the co-existence of austenite and martensite while subsurface layer was predominantly consisting of lath martensite. This indicates that major phase in the nitrided layer is martensitic in nature and nitrogen supersaturation leads to transformation of small fraction of martensite to expanded austenite. © 2016 Elsevier LtdItem Synthesis and characterization of graphene quantum dots and their size reduction using swift heavy ion beam(Taylor and Francis Inc. 325 Chestnut St, Suite 800 Philadelphia PA 19106, 2018) Mishra, P.; Badekai Ramachandra, B.R.Graphene quantum dots (GQDs) are nanosized fragments of graphene displaying quantum confinement effect. They have shown to be prepared from various methods which include ion beam etching of graphene. However, recently the modification of the GQDs has garnered tremendous attention owing to its suitability for various applications. Here, we have studied the effect of swift ion beam irradiation on the properties of GQDs. The ion beam treatment on the GQDs exhibited the change in observed photoluminescence of GQDs as they exhibited a blue luminescence on excitation with longwave UV (?365 nm) due to the reduction in size and removal of the ethoxy (–C–O–C–) groups present on the quantum dots. This was confirmed by transmission electron microscopy, particle size analysis, and Fourier transform infrared spectroscopy. © 2018 Informa UK Limited, trading as Taylor & Francis Group.Item Insights into formation of gradient nanostructured (GNS) layer and deformation induced martensite in AISI 316 stainless steel subjected to severe shot peening(Elsevier B.V., 2018) Jayalakshmi, M.; Huilgol, P.; Badekai Ramachandra, B.R.; Udaya Bhat, K.Severe peening is a well-accepted top-down approach to engender surface nanocrystallization in austenitic stainless steels. In the present study, AISI 316 grade austenitic stainless steel is subjected to severe peening through air blast shot peening technique. Study is aimed at analyzing the microstructural features of the peened layer and deformation induced martensite through transmission electron microscopy technique. Gradient nanostructured (GNS) layer formed as a result of high strain rate, multi-directional deformation during severe peening found to extend to about 500 ?m from the surface. Nucleation of deformation induced martensite is not limited to shear band intersections as affirmed by the published literature related to severe peening. It is observed to nucleate at multiple locations in the austenite matrix. Martensite units thus formed, coalesce with each other to form continuous layer of lath martensite layer at about 15–20 ?m from the surface. Upon further deformation, lath morphology transforms to dislocation cell-type; resulting in fine martensite crystallites at the topmost layer of the peened surface. © 2018 Elsevier B.V.