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Author: search.filters.author.Badekai Ramachandra, B.Subject: search.filters.subject.Chelation

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    Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands
    (2011) Rudresha, B.J.; Badekai Ramachandra, B.; Sampath Kumar, H.C.; Shivakumar, K.I.; Safakath, K.; Philip, R.
    This research article describes the synthesis, characterization and third-order nonlinear optical studies of copper(I) complexes [Cu(Br)(N,N?-C12H6N2O2) (PPh3)] and [Cu(I)(N,N?-C12H6N 2O2)(PPh3)] abbreviated as [CuBrLPPh 3] (1) and [CuILPPh3] (2) (L = 1,10-phenanthroline-5,6- dione). Nonlinear optical properties of the complexes are investigated at 532 nm using single beam Z-scan and degenerate four-wave mixing (DFWM) techniques employing nanosecond laser pulses. The complexes show optical limiting behaviour due to "effective" two-photon absorption. The values of the effective two-photon absorption (2PA) coefficients (?), third-order nonlinear susceptibilities (?(3)), and figures of merit (F), are calculated. © 2010 Elsevier B.V. All rights reserved.