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Item Antibiofouling hollow-fiber membranes for dye rejection by embedding chitosan and silver-loaded chitosan nanoparticles(Springer Verlag, 2019) Kolangare, I.M.; Isloor, A.M.; Zulhairun, Z.A.; Kulal, A.; A.F., A.F.; Siddique, I.; Asiri, A.M.The removal of toxic dyes from the wastewater and industrial effluents is a major environmental challenge. Various techniques have been employed for the removal of dyes, including the application of nano-sized adsorbents, nanocomposite membranes and photodegradation. Membrane filtration is an alterntive but suffers from drawbacks such as fouling. Here we present a simple approach for the development of antibiofouling membranes based on chitosan. The application of chitosan-based nanoparticles as additives for wastewater treatment is poorly explored. The chitosan and silver-loaded chitosan nanoparticles were synthesized by ionic gelation method and incorporated to fabricate hollow-fiber membranes by dry–wet spinning technique. The prepared membranes were characterized by morphological study, permeability test, antibiofouling study and dye rejection study. The nanocomposite hollow-fiber membranes displayed superior performance than their pristine form. The incorporation of 0.30 weight percent of the chitosan and silver-loaded chitosan nanoparticles into the hollow-fiber membranes enhanced the antifouling property with flux recovery ratio of 81.21 and 86.13%, respectively. The dye rejection results showed maximum rejection of 89.27 and 86.04% for Reactive Black 5 and Reactive Orange 16, respectively. Hence, it can be concluded that hollow-fiber membranes with silver-loaded chitosan nanoparticles are pertinent in developing antibiofouling membranes for the treatment of industrial dye effluents. © 2018, Springer Nature Switzerland AG.Item Novel polyphenylsulfone (PPSU)/nano tin oxide (SnO2) mixed matrix ultrafiltration hollow fiber membranes: Fabrication, characterization and toxic dyes removal from aqueous solutions(Elsevier B.V., 2019) Nayak, M.C.; Isloor, A.M.; Siddique, I.; Balakrishna Prabhu, B.; Ismail, N.I.; Asiri, A.M.Novel polyphenylsulfone (PPSU)/nano tin oxide (SnO2) mixed matrix hollow fiber membranes (HFMs) were fabricated by dry-wet spinning via phase separation method. In the current research, reported the contrast between neat PPSU membrane and nanocomposite membranes (PPSU/SnO2), to determine the toxic reactive dyes namely, reactive black-5 (RB-5) and reactive orange-16 (RO-16) removal ability from the aqueous media. Scanning electron microscopy (SEM) was used to observe the HFMs cross-sectional morphological changes and surface roughness parameters of membranes were analyzed using atomic force microscopy (AFM). The surface wettability ability of HFMs was examined with a contact angle, water uptake, and porosity measurements. The cross-flow filter unit was engaged to quantify the water permeability, anti-fouling ability as well as the dye rejection ability of fabricated membranes. With increasing the SnO2 NPs wt% in PPSU polymer matrix the membrane performance was enhanced continuously, it became evident that the incorporated SnO2 NPs plays main role in membrane performance. Added, water-soluble poly (vinylpyrrolidone) (PVP) can also impact the pore morphology in membranes. At the end, PS-3 membrane exhibited lower contact angle (63.7 0), higher water uptake (74.8%), porosity (84.1%), pure water flux 362.9 L/m2 h, and high potential for dyes rejection application, of about >94% for RB-5, and >73% for RO-16 dye, respectively. From the preliminary results, it can be stated that the usage of SnO2 NPs in membrane technology become effective towards wastewater treatment. © 2019 Elsevier B.V.