Faculty Publications

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Publications by NITK Faculty

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Author: search.filters.author.Amaresh, S.P.Subject: search.filters.subject.Empirical equations

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    Liquid-liquid equilibrium of poly(ethylene glycol) 4000 + diammonium hydrogen phosphate + water at different temperatures
    (2008) Amaresh, S.P.; Murugesan, S.; Iyyaswami, I.; Murugesan, T.
    Liquid-liquid equilibrium for an aqueous two-phase system containing poly(ethylene glycol) 4000 + diammonium hydrogen phosphate + water was studied at four different temperatures of (25, 30, 35, and 45)°C. The binodal curve was fitted to three different empirical equations relating the concentrations of PEG 4000 and diammonium hydrogen phosphate, and the coefficients were estimated for the respective temperatures for all three equations. The effective excluded volume values were obtained from the binodal model for the present system, and salting-out ability of the salt was discussed. Tie line compositions were correlated using the Othmer-Tobias and Bancroft equations, and the parameters are also reported. Further, the experimental binodal data of the poly(ethylene glycol) 4000 + diammonium hydrogen phosphate + water system were compared to poly(ethylene glycol) 6000 + diammonium hydrogen phosphate + water for (25, 35, and 45)°C. © 2008 American Chemical Society.
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    Liquid-liquid equilibrium of poly(ethylene glycol) 6000 + triammonium citrate + water systems at different temperatures
    (2009) Iyyaswami, I.; Murugesan, S.; Govindarajan, R.; Amaresh, S.P.; Murugesan, T.
    Liquid - liquid equilibrium for an aqueous two-phase system containing poly(ethylene glycol) 6000 + triammonium citrate + water was studied at five different temperatures, (25, 30, 35, 40, and 45) °C. The binodal curve was fitted to an empirical equation relating the concentrations of PEG 6000 and triammonium citrate, and the coefficients were estimated for the respective temperatures. The effective excluded volume values were obtained from the binodal data. Tie line compositions were estimated and correlated using Othmer - Tobias and Bancroft equations, and the parameters are reported. © 2009 American Chemical Society.
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    Densities and viscosities of polyethylene glycol 6000 + triammonium citrate + water systems
    (2009) Iyyaswami, I.; Govindarajan, R.; Amaresh, S.P.; Murugesan, T.
    The densities and viscosities of binary and ternary solutions of the aqueous two-phase systems created by the polyethylene glycol 6000 + triammonium citrate + water system were measured at different temperatures [(25, 30, 35, 40, and 45) °C] and correlated with empirical equations. The density data were compared with those available in the literature. The density data show a linear variation with the mass fraction of the polymer for all temperatures. The density and viscosity of the top and bottom phases were also measured and reported. © 2009 American Chemical Society.