Journal Articles
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Item Thermal degradation and swelling of thermoplastic vulcanizates from NBR/SAN and NBR/Scrap computer plastics blends(Huthig GmbH, 2009) Anandhan, S.; Rajeev, R.S.; De, S.K.; Bhowmick, A.K.Thermoplastic elastomeric blends of nitrile rubber (NBR)/poly(styrene- coacrylonitrile) (SAN) and NBR/scrap computer plastics (SCP) based on acrylonitrile-butadiene-styrene terpolymer (ABS) were prepared. Thermoplastic elastomeric blends of NBR/SAN containing various amounts of a model waste nitrile rubber powder (w-NBR) were also prepared. Thermogravimetric analysis of the above blends was performed in a nitrogen atmosphere. Both Friedman and Flynn-Wall-Ozawa methods were used for the evaluation of activation energies of thermal degradation of these blends. The dynamically vulcanised blends exhibit higher amount of activation energies for thermal degradation than the unvulcanised ones. Swelling studies were performed in various solvents having different solubility parameter values and maximum swelling was found to occur in a solvent having a solubility parameter that was closer to that of the blend components, i.e., around 20MPa1/2. Dynamically vulcan-ised blends show excellent resistance to IRM #903 oil as well as four chosen solvents possessing different solubility parameters (E).Item Modelling, analysis and optimization of adsorption parameters for H3PO4 activated rubber wood sawdust using response surface methodology (RSM)(2009) Helen Kalavathy, M.H.; Iyyaswami, I.; Ganesapillai, M.G.; Miranda, L.R.Adsorption capacity of Cu2+ from aqueous solution onto H3PO4 activated carbon using rubber wood sawdust (RSAC) was investigated in a batch system. Kinetic and isotherm studies were carried out, the thermodynamic parameters like standard Gibb's free energy (?G°), enthalpy (?H°) and entropy (?S°) were evaluated. The pseudo-second-order model was found to explain the kinetics of Cu2+ adsorption most effectively. The process optimization was performed through Central Composite Rotary Design using response surface methodology (RSM) by Design Expert Version 5.0.7 (STAT-EASE Inc., Minneapolis, USA). An initial concentration of 35 mg L-1, temperature of 26 °C, carbon loading of 0.45 g (100 mL)-1, adsorption time 208 min and pH of 6.5 was found to be the optimum conditions for the maximum uptake of copper ions of 5.6 mg g-1 in batch mode. © 2009 Elsevier B.V. All rights reserved.Item Behavior of sandwich beams with functionally graded rubber core in three point bending(2011) Doddamani, M.R.; Kulkarni, S.M.; KishoreThe three-point bending behavior of sandwich beams made up of jute epoxy skins and piecewise linear functionally graded (FG) rubber core reinforced with fly ash filler is investigated. This work studies the influence of the parameters such as weight fraction of fly ash, core to thickness ratio, and orientation of jute on specific bending modulus and strength. The load displacement response of the sandwich is traced to evaluate the specific modulus and strength. FG core samples are prepared by using conventional casting technique and sandwich by hand layup. Presence of gradation is quantified experimentally. Results of bending test indicate that specific modulus and strength are primarily governed by filler content and core to sandwich thickness ratio. FG sandwiches with different gradation configurations (uniform, linear, and piecewise linear) are modeled using finite element analysis (ANSYS 5.4) to evaluate specific strength which is subsequently compared with the experimental results and the best gradation configuration is presented. © 2011 Society of Plastics Engineers.Item Response of fly ash-reinforced functionally graded rubber composites subjected to mechanical loading(2012) Doddamani, M.R.; Kulkarni, S.M.A novel approach to estimate the Young's modulus of a functionally graded rubber composite (FGRC) from the damping ratio is demonstrated with the examples of unreinforced and fly ash-reinforced materials. FGRC coupons were prepared using the conventional casting technique. The occurrence of gradation in the specimens was attributed to the variable density of particles present in the fly ash, settling at different depths. The technique of free vibrations was used for experimentation. The damping response of the FGRC specimens was studied. The results obtained from the experiments showed that, with growing filler weight fraction, the Young's modulus of the composite increased. The empirical model developed to predict the magnitude of the modulus turned out to be in good agreement with experimental data. © 2012 Springer Science+Business Media, Inc.Item Full scale experiment and finite element modeling of support structures of substation equipment for evaluation of ground motion amplification(2012) Nandam, S.; Ramesh Babu, R.; Venkataramana, K.Post earthquake performance of porcelain insulators installed for high voltage substation equipment, in general, revealed their vulnerability to failure, not due to any quality deficiency, but due to failure of their supporting structures. Most of the equipment in standalone state, withstood to tests of induced vibrations conforming to International standards. The same tested equipment, when erected in position over its supporting structure failed to sustain earthquake ground accelerations, as the supporting structure adversely contributed to amplification of the ground seismic motions while traversing to the top of the structure or the base of the insulator. This paper critically examines salutary effects of damping of vibrations on a typical instrument- transformer, using a rubber based elastic damper, with particular reference to the connected porcelain insulators, in partial containment of amplification of earthquake acceleration or in minimizing attendant distress on them. The analytical study carried out is based on experimental studies conducted on the equipment using shake table and then correlating the results obtained using finite element analysis, on the full scale model to draw meaningful conclusions. © 2012 CAFET-INNOVA TECHNICAL SOCIETY.Item Compressive properties of sandwiches with functionally graded rubber core and jute-epoxy skins(2013) Doddamani, M.R.; Kulkarni, S.The compressive behaviour of a new class of sandwich composite made up of jute fiber reinforced epoxy skins and piece-wise linear fly ash reinforced functionally graded (FG) rubber core is investigated in flat-wise mode. FG samples are prepared using conventional casting techniéue. Presence of gradation is éuantified physically by weight method. This paper addresses the effect of weight fraction of fly ash, core to thickness ratio (C/H) and orientation of jute on specific compressive modulus and strength. In each trial five replicates are tested with lower amount of fly ash below the upper skin of sandwich (rubber-up). Results of experimentation are subjected to statistical analysis of variance (ANOVA) to find the influential factor governing the compressive behaviour. Furthermore piece-wise linear gradation is modeled in finite element and strength values are compared with experimental results. Sandwich sample with fly ash content of 40%, C/H of 0.4 and orientations of 30?/60? registered better performance. Specific strength is observed to increase upto 30% filler content followed by stabilization. Finite element results for strength match very well with experimental ones.Item Thermoplastic vulcanizates from post consumer computer plastics/nitrile rubber blends by dynamic vulcanization(Springer Japan, 2013) Anandhan, S.; Bhowmick, A.K.Due to depletion of natural resources and increasing greenhouse emissions, new technologies for the transformation of waste polymers into valuable materials represent one of our greatest current needs. Acrylonitrile-butadiene-styrene terpolymer (ABS) is one of the most widely used engineering plastics and is used as outer casing for electronic equipment. Nitrile rubber (NBR) is used in many applications that demand oil resistance. In an attempt to explore whether these materials can be successfully recycled, we prepared blends of scrap computer plastics (SCP) based on ABS with NBR and waste NBR powder (w-NBR), and investigated their mechanical properties and recyclability. Specifically, we assessed the effect of dynamic vulcanization and replacement of virgin NBR with w-NBR on the properties of 60/40, 70/30, and 80/20 NBR/SCP blends. These blends exhibited thermoplastic elastomeric behavior. The thermoplastic elastomeric blends showed excellent swelling resistance to standard lubricant oil (namely, IRM 903 oil). © 2013 Springer Japan.Item A novel approach to investigate effect of magnetic field on dynamic properties of natural rubber based isotropic thick magnetorheological elastomers in shear mode(Central South University of Technology f-ysxb@mail.csut.edu.cn, 2015) Hegde, S.; Kiran, K.; Gangadharan, K.V.The preparation of natural rubber based isotropic thick magnetorheological elastomers (MRE) was focused on by varying the percentage volume concentration of carbonyl iron powder and developing a test set up to test the dynamic properties. Effect of magnetic field on the damping ratio was studied on the amplification region of the transmissibility curve. The viscoelastic dynamic damping nature of the elastomer was also studied by analyzing the force-displacement hysteresis graphs. The results show that MR effect increases with the increase in magnetic field as well as carbonyl iron powder particle concentration. It is observed that softer matrix material produces more MR effect. A maximum of 125% improvement in the loss factor is observed for the MRE with 25% carbonyl iron volume concentration. FEMM simulation shows that as carbonyl iron particle distribution becomes denser, MR effect is improved. FEMM analysis also reveals that if the distance between the adjacent iron particles are reduced from 20 ?m to 10 ?m, a 40% increase in stored energy is observed. © 2014, Central South University Press and Springer-Verlag Berlin Heidelberg.Item Experimental investigation on slurry erosive behaviour of biodegradable flexible composite and optimization of parameters using Taguchi's approach(Lavoisier, 2018) Mahesh, V.; Joladarashi, S.; Kulkarni, S.M.In the present study, the emphasis is on analysing the slurry erosive behaviour of novel green flexible composite made from jute fiber and natural rubber of ribbed smoke sheet (RSS) grade. The bonding gum made of natural rubber is used to bind the fiber and RSS rubber. Three different stacking sequences namely jute-rubber-jute (JRJ), jute-rubber-rubberjute (JRRJ) and jute-rubber-jute-rubber-jute (JRJRJ) are considered. Erosive studies are carried out on the prepared composites under three different rotation speeds (500, 1000 and 1500 rpm) and three different sand concentration (50, 75 and 100 gms) with silica sand as the abrasive medium dispersed in tap water. Design of experiments (DOE) is carried out using Taguchi's L9 orthogonal array on slurry erosion test to find out the effect of the stacking sequence, rotation speed and sand concentration on the weight loss of the composite. Through ANOVA, it was concluded that sand concentration is the main factor affecting the weight loss of composite. Regression model is developed and it was found that the developed model is adequate and feasible to predict the weight loss due to slurry erosion within the range of experimental conditions. © 2018 Lavoisier. All rights reserved.Item Investigation on the eect of using rubber as core material in sandwich composite plate subjected to low-velocity normal and oblique impact loadings(Sharif University of Technology, 2019) Mahesh, V.; Joladarashi, S.; Kulkarni, S.M.In this article, the structural performance of composite plate under low-velocity impact is studied. Two forms of layup sequence, namely, Jute-Epoxy laminate (JE) and Jute-Epoxy-Rubber sandwich (JE-R-JE), were considered for evaluation. Special emphasis was on evaluating the inuence of normal and oblique loadings. Various dynamic parameters, such as energy, peak load, and deformation, were analysed in detail to study the eect of impact angle on both laminate and sandwich structures. Stress analysis of both laminate and sandwich structures was carried out to discuss the eect of introducing rubber as a core material. The results revealed that using rubber as a core material had a signicant eect on energy absorption. In addition, it was noticed that increasing the angle of impact would yield better performance of the composite plate. The results presented here may serve as benchmark for eective utilization of composite plates in low-velocity impact applications. © 2019 Sharif University of Technology. All rights reserved.