Journal Articles
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Item Acid, alkali and chloride resistance of high volume fly ash concrete(Indian Society for Education and Environment indjst@gmail.com, 2015) Sahoo, S.; Das, B.B.; Rath, A.K.; Kar, B.B.Objectives: To find variation in compressive strength and mass of high volume fly ash concrete samples subjected to different chemical solutions of sodium chloride, sodium sulphate and sulphuric acid. Methods: A total of 900 numbers of cubes were cast and cured with four levels of curing period of 28, 56, 90 and 120 days. After certain duration of curing period, specific numbers (60) of cubes were submerged each in 5 percent sodium sulphate solution (Na2SO4), 5 percent sodium chloride solution (NaCl) and 1percent of sulphuric acid solution (H2SO4) separately in chemical exposure containers for an exposure period of 30, 60, 90 and 120 days. Findings: Investigations with respect to acid, alkali and chloride resistance were carried out on high volume fly ash concrete, HFC (40 percent replacement with cement), low volume fly ash concrete, LFC (25 percent replacement with cement) and their performances against control concrete (NC) is presented in this paper. Their performance was measured with respect to the loss in compressive strength and weight of the concrete cubes over the period of exposure time. It is found that the resistance of control concrete to all the three chemical attack is better only up to 28 days of water curing. At 56 days of water curing LFC shows better resistance against the control and HFC. However, with prolonged water curing of cubes of 90 days and more, HFC has consistently shown highest resistance; whereas the control concrete faced a great loss in strength.Item Acid, alkali, and chloride resistance of concrete composed of low-carbonated fly ash(American Society of Civil Engineers (ASCE) onlinejls@asce.org, 2017) Sahoo, S.; Das, B.B.; Mohammed Mustakim, S.This research investigates the effect of carbonated fly ash inclusion in concrete as partial replacement of cement on the durability performance when exposed to salt, sulfate, and acid solution. The effect of chemical exposure periods (30, 60, 90, and 120 days) on compressive strength and weight of concrete with low volume (25%) replacement of cement was investigated for various water curing ages (28, 56, 90, and 180 days). A comparative assessment with low volume (25% cement replacement) fly ash concrete and control concrete was also conducted. It was observed from the results that low volume carbonated fly ash concrete demonstrated a significant increase in resistance to loss in compressive strength and weight against salt, sulfate, and acid attack. Gray relation-based analysis was performed to determine suitable parameters for simultaneous minimization of strength loss and weight loss under chemical exposure. It can be recommended that, due to its cost-effectiveness, easy processing, and environmental friendly nature, carbonated fly ash can be adopted in construction as a partial replacement of cement in concrete. © 2016 American Society of Civil Engineers.Item Determination of optimized geopolymerization factors on the properties of pelletized fly ash aggregates(Elsevier Ltd, 2018) Shivaprasad, K.N.; Das, B.B.This research investigates the effect of geopolymerization factors on the pelletization in the production of artificial fly ash aggregates. The proportion of pelletized fly ash aggregate mixes was designed through Taguchi's L9 orthogonal array. The properties of the aggregates produced from the optimal mixes were characterized according to the standard specifications. The effect of geopolymerization factors such as Na2O content, water content, and curing regime on the properties of the pelletized fly ash geopolymer aggregates was determined through response indices at the age of 14, 28 and 56 days. In addition, Grey relation based analysis was performed to identify the most critical parameter for optimization among three geopolymerization factors selected in this investigation, for the production of pelletized fly ash geopolymer aggregates. It is observed from the response indices and Grey relation results that the impact value of the aggregates and crushing strength of individual pellets is governed by heat curing and high water content at the age of 14 and 28 days. However, at the age of 56 days these response indices are significantly governed by the solution curing and high water content. It was also noted that the minimum Na2O content of 3.5–4.5% is adequate for the production of pelletized fly ash aggregates. © 2017 Elsevier LtdItem Influence of fineness of fly ash on compressive strength and microstructure of bottom ash admixed geopolymer mortar(Associated Cement Companies Ltd., 2018) Shivaprasad, K.N.; Das, B.B.; Renjith, R.Investigations were conducted to find out the suitability of bottom ash as a possible replacement to fine aggregates in geopolymer mortar. Experimental work was done to study the influence of fineness of fly ash (with three levels of Blaine's fineness, 2043 cm2/g, 2602 cm2/g and 3113 cm2/g on compressive strength and microstructure development of fly ash based geopolymer mortar with natural river sand and bottom ash as fine aggregates. three different water to solids ratios of 0.246, 0.349, and 0.443 were chosen for this study and the curing of the specimens was at ambient temperature (28 ± 3°c). compressive strength development for all eighteen mortar mixes was measured at 7, 14, 28 and 56 days. Further, the effect of fineness of fly ash on degree of polymerization, microstructure and properties of geopolymers was studied using Fourier transform Infrared Spectroscopy (FtIR) and Scanning Electron Microscopy (SEM). It was observed from the compressive strength of the geopolymer mortar that the degree of polymerization is gradual for both types of mortar. there is a continuous increase in the development of compressive strength noticed till the age of 56 days for both types of mortar, sand as well as bottom ash admixed. However, the increment of compressive strength for bottom ash found to be significantly less as compared to natural sand. Improvement in compressive strength due to fineness of fly ash were characterised by SEM and FtIR and it is revealed that with increase in fineness levels, the microstructure significantly enhanced the characteristics of geopolymer mortar. © 2018 Associated Cement Companies Ltd.. All rights reserved.Item Early age, hydration, mechanical and microstructure properties of nano-silica blended cementitious composites(Elsevier Ltd, 2020) Snehal, K.; Das, B.B.; Akanksha, M.This study was carried out to understand the influence of nano-silica on hydration properties of binary, ternary and quaternary blended cement paste and mortar containing micro to nano sized admixtures including fly ash (FA), ultrafine fly ash (UFFA) and nano-silica in colloidal form (CNS). Characterization methods such as thermogravimetric analysis (TGA), X-ray diffraction studies (XRD) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) was employed to quantify the hydration products. Further, early age and mechanical properties were also investigated for binary, ternary and quaternary cementitious system blended with nano-silica. The optimized proportions of blended paste and mortar are designed through modified Andreasen and Andersen particle packing model. The experimental test results revealed that the optimum dosage of CNS in binary blended cement composites is 3%. The presence of nano-silica in cementitious system amplified the hydration and pozzolanic activity, thereby promoting densified microstructure at nano scale. The flow test indicated the intensified demand for water absorption and reduced workability with the rise in level of incorporation of CNS particles in cement paste. Quaternary blended mix performed superior hydration along with strength properties amongst all the blended samples. © 2019 Elsevier LtdItem Pozzolanic Reactivity, Hydration and Microstructure Characteristics of Blended Cementitious Composites Comprising of Ultrafine Particles(Springer Science and Business Media Deutschland GmbH, 2022) Snehal, K.; Das, B.B.; Sudhi, A.; Pandey, D.Performance of ultrafine fly ash (UFFA, 5–10 µm) and fly ash (FA, 45–50 µm) particles in cementitious composites was investigated individually as well as in combination. To study the physicochemical behaviour of blended cementitious composites, engineering properties and pozzolanic reactivity test were conducted. Further, characterization techniques such as thermogravimetric analysis (TGA), X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDX) were employed. The results showed good amplification in the development of early compressive strength and durability on admixing ultrafine particles of fly ash (UFFA) in cementitious system. Particle size and specific surface area of UFFA greatly influenced on the phase assemblages of cementitious composites, i.e. due to enriched pozzolanic reactivity which reduced Ca/Si atomic ratio (≤ 1.82) in the pore solution of cementitious matrix. On contrary, the presence of UFFA particles in cementitious composite mix developed disjoining pressure in addition to self-desiccation thereby induced early age cracks and also reduced the workability in correspondence to that of FA particles. Further, use of UFFA in conjunction with FA particles, cementitious composites showed much superior performance in terms of both physical and chemical characteristics, which necessitates the crucial need of admixing micron and submicron size particles in the design of sustainable and high-performance cementitious composites at this point of time. © 2022, The Author(s), under exclusive licence to Shiraz University.Item Pelletisation factors on the production of fly-ash aggregates and its performance in concrete(ICE Publishing, 2023) Shivaprasad, K.N.; Das, B.B.; Sharath, B.P.This research study investigates the factors associated with pelletisation in the production of fly-ash aggregates and its performance in concrete. To investigate this influence, experiments were carried out in different stages to explore the effect of factors responsible for pelletisation, which were designed through Taguchi’s experimental design. Additionally, the influence of each parameter on the engineering properties of the produced aggregates was determined using Grey relational analysis. Further, considering the optimised pelletisation factors of the laboratory-scale studies and with the help of an industrial-scale pelletiser, mass production of fly-ash aggregates was carried out and characterised for their engineering properties. The test results indicate that these aggregates are mainly governed by water content followed by the angle and speed of pelletizing disc. It is observed from the results that the engineering properties of aggregates produced on an industrial scale are found to be better than sintered aggregates and also comparable with that of natural aggregates except for water absorption. The properties of concrete produced with fly-ash aggregates, light weight sintered aggregates and natural aggregates were also studied. The results showed that properties of concrete produced with fly-ash aggregates are in good correlation with those of conventional concrete produced with natural aggregates. © 2023 ICE Publishing. All rights reserved.Item Influence of Integration of Iron Ore Tailings on the Physio-mechanical and Microstructure Properties of Fly Ash Based Coarse Aggregates(ASTM International, 2023) Sharath, B.P.; Nikunj, P.; Das, B.B.The goal of this experimental study is to produce fly ash (FA)-based coarse aggregates by adding iron ore tailings (IOT) to the FA-based precursor as an additional mix component. The involvement of different types of binders - influential factors of both pelletization and geopolymerization that govern the production of FA-based coarse aggregates - was experimentally designed by adopting Taguchi's experimental design. An evaluation was conducted utilizing response indexes at three curing periods to study the accumulation of all the influencing factors in the production process as well as on the engineering features of IOT admixed FA-based coarse aggregates. Aggregate impact and crushing values, individual pellet strength (IPS), and specific gravity and water absorption values were measured. According to experimental findings, IOT addition considerably affects the engineering characteristics of FA-based coarse aggregates. The heat resistance of the produced aggregates was found to be improved by the presence of different sodium oxide dosages and blending ratios (IOT:FA) based on analysis through scanning electron microscopy and thermogravimetric differential thermal analysis. The role of IOT in associative formation of calcium silicate hydrate is demonstrated by increasing calcium hydroxide, which supports increasing IPS values of produced aggregates. From the 1st to the 200th day of curing age, Fourier-transform infrared spectroscopy studies between the best- and worst-performing mixes showed two things: first, the emergence of new peaks with time, and second, the observation of major bands shifting to lower and higher wavenumbers, which was found to be directly correlated to the performance of the aggregates. © 2023 ASTM International. All rights reserved.Item Research on Setting Time, Compressive Strength and Microstructure of Fly Ash-Based Geopolymer Mixture Containing Slag(Springer Science and Business Media Deutschland GmbH, 2023) Prasanna, K.M.; Sharath, B.P.; Choukade, H.; Shivaprasad, K.N.; Das, B.B.; Mahesh, G.This study focusses on upgrading the fresh and hardened properties of fly ash-based geopolymer mix samples such as initial and final setting time, flow table test and compressive strength with the substitution of ground granulated blast furnace slag at varied percentage levels and with different alkali binder ratios. Substitution of slag in geopolymer mix samples is important so as to achieve fast setting characteristics in the product. For studying these effects on the microstructure of the product, scanning electron microscopy (SEM) with energy dispersive spectroscopy and Fourier transform infrared spectroscopy were conducted. The experimental outcomes stated that an increase in slag substitution has decreased the setting time and increased the compressive strength of geopolymer mix samples. SEM images have revealed the occurrence of a dense matrix with the slag substitution. FTIR results stated that shifting in wavenumbers of characteristic bands to lower numbers for varied slag substitution levels indicates a greater extent of geopolymerization. © 2022, The Author(s), under exclusive licence to Shiraz University.Item Synergistic effect of nano silica on carbonation resistance of multi-blended cementitious mortar(Elsevier Ltd, 2023) Snehal, K.; Das, B.B.; Barbhuiya, S.Confiscation of alkaline buffer in a blended cementitious system surges the risk of carbonation. Understanding the carbonation mechanism and kinetics of multi-blended cementitious systems in correspondence to microstructural properties is the need of the hour. In this context, the change in the microstructure of binary, ternary, and quaternary blended cementitious mortar mix comprising of fly ash or/and ultra-fine fly ash or/and nano-silica upon accelerated carbonation (3.5% CO2; 70% RH) was studied. All multi-blended mixes were proportioned using modified Andreasen and Andersen particle packing theory. Permeable porosity and carbonation parameters such as carbonation depth, rate of change in compressive strength, and carbonation shrinkage were measured. Further, qualitative/quantitative estimation of carbonation phases was done using characterization techniques such as TGA and FTIR. In control mix with solely OPC, the reaction of CO2 with calcium-bearing phases showed chemo-mechanical changes leading to 18% improvement in strength at 30 days of exposure. The optimized multi-blended cementitious systems with nano-silica exhibited higher resistance to carbonation kinetics. Phase assemblages quantified through TGA within depth of carbonation imply a negligible concentration of portlandite (CH). However, mixes without nano-silica exhibited a significant reduction in bound water content associated with C–S–H/AFt/AFm phases and intensified the precipitation of calcium carbonate (CaCO3) phase. Asymmetric stretching band of C–O–C at 1424 cm−1 corresponding to calcite phase measured using FTIR validates the outcomes of TGA. © 2023 Elsevier Ltd