Journal Articles
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Item A comprehensive review on the use of hemp in concrete(Elsevier Ltd, 2022) Barbhuiya, S.; Das, B.B.A simple mixture of hemp hurd, water, and lime is used to make hemp concrete. It is indeed one of the few materials that can continue to absorb carbon after being employed in construction, storing more carbon in the atmosphere over the building's lifetime than was emitted during construction. Furthermore, hemp can be harvested in as little as 60 days. Hemp concrete is a “carbon-negative” or “better-than-zero-carbon” substance because the hemp plant absorbs more carbon from the atmosphere than it emits during its production and application on site. It is a bio-composite material that can be utilised as an alternative to concrete and standard insulation in building. Hemp concrete is also recyclable at the end of the building's lifespan. This study summarises the fast-developing body of knowledge about hemp concrete, which was recently developed. © 2022 Elsevier LtdItem Acid, alkali and chloride resistance of high volume fly ash concrete(Indian Society for Education and Environment indjst@gmail.com, 2015) Sahoo, S.; Das, B.B.; Rath, A.K.; Kar, B.B.Objectives: To find variation in compressive strength and mass of high volume fly ash concrete samples subjected to different chemical solutions of sodium chloride, sodium sulphate and sulphuric acid. Methods: A total of 900 numbers of cubes were cast and cured with four levels of curing period of 28, 56, 90 and 120 days. After certain duration of curing period, specific numbers (60) of cubes were submerged each in 5 percent sodium sulphate solution (Na2SO4), 5 percent sodium chloride solution (NaCl) and 1percent of sulphuric acid solution (H2SO4) separately in chemical exposure containers for an exposure period of 30, 60, 90 and 120 days. Findings: Investigations with respect to acid, alkali and chloride resistance were carried out on high volume fly ash concrete, HFC (40 percent replacement with cement), low volume fly ash concrete, LFC (25 percent replacement with cement) and their performances against control concrete (NC) is presented in this paper. Their performance was measured with respect to the loss in compressive strength and weight of the concrete cubes over the period of exposure time. It is found that the resistance of control concrete to all the three chemical attack is better only up to 28 days of water curing. At 56 days of water curing LFC shows better resistance against the control and HFC. However, with prolonged water curing of cubes of 90 days and more, HFC has consistently shown highest resistance; whereas the control concrete faced a great loss in strength.Item Acid, alkali, and chloride resistance of concrete composed of low-carbonated fly ash(American Society of Civil Engineers (ASCE) onlinejls@asce.org, 2017) Sahoo, S.; Das, B.B.; Mohammed Mustakim, S.This research investigates the effect of carbonated fly ash inclusion in concrete as partial replacement of cement on the durability performance when exposed to salt, sulfate, and acid solution. The effect of chemical exposure periods (30, 60, 90, and 120 days) on compressive strength and weight of concrete with low volume (25%) replacement of cement was investigated for various water curing ages (28, 56, 90, and 180 days). A comparative assessment with low volume (25% cement replacement) fly ash concrete and control concrete was also conducted. It was observed from the results that low volume carbonated fly ash concrete demonstrated a significant increase in resistance to loss in compressive strength and weight against salt, sulfate, and acid attack. Gray relation-based analysis was performed to determine suitable parameters for simultaneous minimization of strength loss and weight loss under chemical exposure. It can be recommended that, due to its cost-effectiveness, easy processing, and environmental friendly nature, carbonated fly ash can be adopted in construction as a partial replacement of cement in concrete. © 2016 American Society of Civil Engineers.Item Influence of fineness of fly ash on compressive strength and microstructure of bottom ash admixed geopolymer mortar(Associated Cement Companies Ltd., 2018) Shivaprasad, K.N.; Das, B.B.; Renjith, R.Investigations were conducted to find out the suitability of bottom ash as a possible replacement to fine aggregates in geopolymer mortar. Experimental work was done to study the influence of fineness of fly ash (with three levels of Blaine's fineness, 2043 cm2/g, 2602 cm2/g and 3113 cm2/g on compressive strength and microstructure development of fly ash based geopolymer mortar with natural river sand and bottom ash as fine aggregates. three different water to solids ratios of 0.246, 0.349, and 0.443 were chosen for this study and the curing of the specimens was at ambient temperature (28 ± 3°c). compressive strength development for all eighteen mortar mixes was measured at 7, 14, 28 and 56 days. Further, the effect of fineness of fly ash on degree of polymerization, microstructure and properties of geopolymers was studied using Fourier transform Infrared Spectroscopy (FtIR) and Scanning Electron Microscopy (SEM). It was observed from the compressive strength of the geopolymer mortar that the degree of polymerization is gradual for both types of mortar. there is a continuous increase in the development of compressive strength noticed till the age of 56 days for both types of mortar, sand as well as bottom ash admixed. However, the increment of compressive strength for bottom ash found to be significantly less as compared to natural sand. Improvement in compressive strength due to fineness of fly ash were characterised by SEM and FtIR and it is revealed that with increase in fineness levels, the microstructure significantly enhanced the characteristics of geopolymer mortar. © 2018 Associated Cement Companies Ltd.. All rights reserved.Item Mechanical and permeability properties of hybrid fibre reinforced porous concrete(Associated Cement Companies Ltd., 2019) Snehal, K.; Das, B.B.Experimental investigation was carried out to determine the enhancement of compressive strength, flexural strength and abrasion resistance along with water permeability of porous concrete introduced with hybrid fibres (consists of equal proportion of steel, polypropylene and glass) and with two different sizes of coarse aggregate. The varying parameters in the preparation of porous concrete mix were coarse aggregate of two sizes, i.e., 6 mm and 12 mm and five different percentages of hybrid fibres (0.25 - 0.65 with an increment of 0.1). Compressive strength and flexural strength were measured at the end of two curing periods (7 and 28 days) whereas water permeability and abrasion test values were measured at the end of 28 days of curing. From the experimental findings, it is observed that compressive strength and flexural strength values increase with decrease in the size of the aggregate for control as well as fibre reinforced porous concrete. However, with respect to the measured values of permeability, it is found that with increase in size of coarse aggregates, permeability values also increases. For 28 days samples it is observed that 0.35% addition of hybrid fibres to porous concrete found to be optimum and it improved the compressive strength values by 20.24% and 19.06% for coarse aggregate sizes of 6mm and 12mm, respectively as compared to porous control concrete (without addition of hybrid fibres). Whereas, maximum flexural strength was obtained at 0.45% of addition of hybrid fibres and 31.6% (6mm coarse aggregate) increment and 24.26% (12mm coarse aggregate) increment were noticed as compared to porous control concrete. The best values for permeability were found at 0.35% of hybrid fibres and 12 mm coarse aggregate combination, whereas for abrasion resistance it was at 0.35% of hybrid fibres and 6mm coarse aggregate combination. © 2019 Associated Cement Companies Ltd.. All rights reserved.Item Effect of elevated temperatures on ferrochrome ash based mortars(Associated Cement Companies Ltd., 2019) Kumar, B.; Yaragal, S.C.; Das, B.B.Due to boom in construction sector, large amount of Ordinary Portland Cement (OPC) is being consumed. Cement production is energy intensive and releases large amount of CO2 into atmosphere. Efforts are on to bring down cement consumption by the use of secondary cementitious materials. An attempt is made to study the influence of combined effect of various levels of ferrochrome ash (FCA) and lime, as replacement to OPC for different cement mortar mixtures at elevated temperatures. FCA replacement considered is in the range of 0% to 20% and along with 7% lime as replacement to cement. Compressive strength of cementitious materials is being an important parameter in the design of structures. The main objective of this work is to assess the residual compressive strengths at different levels of temperatures (200, 400, 600, and 800ºC) for a retention period of half an hour. Residual strengths of mortar mixtures produced, using FCA, have shown a good performance. Upto 20% FCA and 7% lime, mixture turns out to be a good elevated temperatures enduring material. This would increase the suggested application for environmental friendly materials. Important differences were seen in microstructural observations with scanning electron microscope (SEM) for various levels of FCA and lime incorporated mortars. © 2019, Associated Cement Companies Ltd. All rights reserved.Item Influence of Integration of Phase Change Materials on Hydration and Microstructure Properties of Nanosilica Admixed Cementitious Mortar(American Society of Civil Engineers (ASCE) onlinejls@asce.org 1801 Alexander Bell DriveGEO Reston VA 20191 Alabama, 2020) Snehal, K.; Das, B.B.; Kumar, S.The present study demonstrates the influence of integrating phase change materials (PCMs) on hydration and microstructure properties of nanosilica admixed cementitious mortar. First, the optimized dosage of nanosilica in correspondence to compressive strength was determined. Subsequently, the desired proportion of PCMs was identified pertaining to a designated compressive strength of 35 MPa at the curing age of 28 days. The hydration and microstructure studies were carried out through thermo gravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM), respectively. Further, thermal properties were determined by means of differential scanning calorimetry (DSC). Incorporation of nanosilica into the cementitious mortar was found to have a positive influence on early strength development and durability, however, there was found to be an increase in chemical shrinkage as compared to the control mixture. PCMs integrated cementitious mortar improved the thermal efficiency as well as reduced the chemical shrinkage, but adversely affected the mechanical, hydration, and durability properties. With respect to development of compressive strength of the cementitious mortar, it is found that n-octadecane PCMs performed better amidst other PCMs, such as paraffin and sodium carbonate hydrates. Further, studies were carried out on cementitious mortar having both nanosilica (optimized proportion) and PCMs (the best performing). From the results, it is found that cementitious mortar comprising of both nanosilica and PCMs have compensated the drawbacks of one another. Blended mortar (having both nanosilica and PCMs) showed superior strength gain at early age, better durability resistance, low chemical shrinkage, and superior thermal performance. © 2020 American Society of Civil Engineers.Item Ferrochrome ash – Its usage potential in alkali activated slag mortars(Elsevier Ltd, 2020) Kumar, K.B.; Yaragal, S.C.; Das, B.B.This study is an attempt to develop a sustainable construction material, i.e., alkali activated slag (AAS) in combination with ferrochrome ash (FCA) as a replacement to ordinary Portland cement (OPC). The effect of the various levels of FCA (0, 25, and 50%) replacing ground granulated blast furnace slag (GGBS) in AAS mortars with 4% of Na2O dosage is studied. Further, five levels of the modulus of silica (Ms = 0.75, 1.00, 1.25, 1.5, and 1.75) are chosen to achieve targeted compressive strength at 28 days under ambient temperature curing conditions. The compressive strength decreases with the increase in level of the FCA replacement. The targeted design compressive strength is achieved with 25% FCA replacement to GGBS in the AAS mortar system with Ms = 1.25. In addition, microstructure and mineralogical studies are undertaken to ascertain the formation of different hydration products with the aid of the scanning electron microscope (SEM) and the X-ray diffractometer (XRD). Gismondine and calcium aluminate silicate hydrate (C-A-S-H) are the major hydration products in the AAS mortar mixes. Sodium aluminate silicate hydrate phases (N-A-S-H) are also observed prominently as the FCA replacement level increases in the AAS mortar mixes. The Fourier-transform infrared spectroscopy (FTIR) confirms the presence of the Si–O-(Si or Al) functional group. The addition of FCA in the AAS system is of vital significance in the reduction of the embodied carbon dioxide (ECO2eq), embodied energy (EEeq) and cost. © 2020 Elsevier LtdItem Potential utilization of regional cashew nutshell ash wastes as a cementitious replacement on the performance and environmental impact of eco-friendly mortar(Elsevier Ltd, 2023) Manjunath, B.; Ouellet-Plamondon, C.M.; Das, B.B.; Bhojaraju, C.Globally, agro-waste ashes are increasing significantly due to the rapid implementation of biomass-based power plants. In the present trend, agro-wastes are disposed of in an unsustainable manner. The recycling of agro-waste has significantly contributed to sustainable goals. In the construction sector, it is possible to dispose of waste more efficiently. However, the efficiency of locally available agro-residual waste in cementitious composites is not well understood. In the present investigation, the practicability of using agro-residual ash obtained from the burning of cashew nutshells on the properties of eco-friendly blended cement paste and mortars is explored. Blended cement mixtures containing cashew nutshell ash (CNSA) were prepared at five replacement levels, 5, 10, 15, 20, and 25%, relative to the weight of the cement. To understand the characteristics of CNSA, microstructure investigations such as X-ray diffraction, thermogravimetric analysis (TGA), scanning electron microscopy, and energy-dispersive spectroscopy analyses were performed. Paste properties of CNSA-based cement are observed through consistency, setting time, mini-slump flow, and expansion tests. For the CNSA-based mortars flow table, compressive strength, ultrasonic pulse velocity (UPV), electrical resistivity (ER), water absorption, bulk density, and porosity tests were performed to understand its efficiency. The strength indices of mortars were used to quantify the pozzolanic effect of CNSA. With the incorporation of CNSA, water demand increased by 57%, initial and final setting time decreased by 90% and 83%, respectively. Results showed that CNSA-based mortars absorbed more water and had higher porosity, which reduced compressive strength, UPV, and ER values. CNSA blended mortar is more suitable for applications that do not require high compressive strength. Results indicated that the compressive strength, UPV, and ER are within the limit specified. Strength indices indicated that CNSA has a positive and negative pozzolanic effect during early and later ages, respectively. Further, the sustainable assessment showed that the introduction of CNSA in mortar could substantially reduce embodied carbon, embodied energy, and strength efficiency over the control mortar. The inadequate amount of SiO2, Fe2O3, and Al2O3 in CNSA makes it an unsuitable pozzolanic material. However, it can be utilized in smaller amounts as a fractional replacement of cement and is found to be promising for specific desired properties of cement as a cost-effective accelerator. © 2023 Elsevier LtdItem Synergistic effect of nano silica on carbonation resistance of multi-blended cementitious mortar(Elsevier Ltd, 2023) Snehal, K.; Das, B.B.; Barbhuiya, S.Confiscation of alkaline buffer in a blended cementitious system surges the risk of carbonation. Understanding the carbonation mechanism and kinetics of multi-blended cementitious systems in correspondence to microstructural properties is the need of the hour. In this context, the change in the microstructure of binary, ternary, and quaternary blended cementitious mortar mix comprising of fly ash or/and ultra-fine fly ash or/and nano-silica upon accelerated carbonation (3.5% CO2; 70% RH) was studied. All multi-blended mixes were proportioned using modified Andreasen and Andersen particle packing theory. Permeable porosity and carbonation parameters such as carbonation depth, rate of change in compressive strength, and carbonation shrinkage were measured. Further, qualitative/quantitative estimation of carbonation phases was done using characterization techniques such as TGA and FTIR. In control mix with solely OPC, the reaction of CO2 with calcium-bearing phases showed chemo-mechanical changes leading to 18% improvement in strength at 30 days of exposure. The optimized multi-blended cementitious systems with nano-silica exhibited higher resistance to carbonation kinetics. Phase assemblages quantified through TGA within depth of carbonation imply a negligible concentration of portlandite (CH). However, mixes without nano-silica exhibited a significant reduction in bound water content associated with C–S–H/AFt/AFm phases and intensified the precipitation of calcium carbonate (CaCO3) phase. Asymmetric stretching band of C–O–C at 1424 cm−1 corresponding to calcite phase measured using FTIR validates the outcomes of TGA. © 2023 Elsevier Ltd