Browsing by Author "Kumar, B.S."

Now showing 1 - 11 of 11

Design of Power Combiner and Power Divider at Ku Frequency Band Applications
(Institute of Electrical and Electronics Engineers Inc., 2023) Kumar, B.S.; Gorre, P.; Babu, B.R.; Samantaray, A.K.; Naik, D.N.; Kumar, S.
This paper presents the design of a Ku band power combiner and divider, operating within the frequency range of 12 GHz to 16 GHz. The power combiner achieves S(1,1) values of -23.17 dB, -19.47 dB, and -20.97 dB at 13 GHz, 13.87 GHz, and 14.77 GHz and S(1,2) values of -11.012dB at 13.98 GHz and S(1,3) value of -12.470 dB at 14.01 GHz and S(2,2) values of - 37.028dB at 13.28GHz respectively. Meanwhile, the power divider achieves S(1,1) values of -40 dB and -33 dB at 12.8 GHz and 13.8GHz and S(1,2) values of -13.173 dB at 13.02GHz and S(1,3) values of -15.590 dB at 13.02GHz and S(2,2) value of -21.744dB at 12.98GHz and S(2,2) value of -17.567 dB at 14.98 GHz respectively. The substrate employed is a 1.6mm thick FR-4 material. Â© 2023 IEEE.
Graphene nanoclusters embedded nickel cobaltite nanofibers as multifunctional electrocatalyst for glucose sensing and water-splitting applications
(2019) Kumar, B.S.; Gudla, V.C.; Ambat, R.; Kalpathy, S.K.; Anandhan, S.
Nickel cobaltite (NCO) attains the apex of Sabatier-type volcano plot for electrochemical reaction compared to simple oxides due to synergetic effect of mixed transition metal cations. The combination of high surface area, aspect ratio, and porosity of electrospun NCO nanofibers (NCO-NF) enhance their electrocatalytic performance by improved electron mobility and more active sites. In the present study, NCO-NF fabricated using poly (styrene-co-acrylonitrile) (SAN) as a sacrificial polymer, were embellished with graphene nanoclusters (GNC), which augment the electrocatalytic performance of the NCO-NF. The in situ formed GNC along the NCO-NF are result of the interaction between the polar functional groups of the polymer, and the cations of precursor salts during the calcination of precursor nanofibers. The GNC/NCO-NF with least crystallite size and high aspect ratio having porous NCO nanoparticles and in situ grown GNC were developed using sol-gel electrospinning process assisted by calcination of precursor nanofibers. This simple, eco-friendly, and economical synthesis route with unique structure chemistry of SAN to form GNC and the presence of dual cations (Ni and Co) provides enhanced performance and multifunctionality to GNC/NCO-NF electrodes for electrocatalytic applications, such as biosensors and water-splitting. In the present study, the modified electrodes (GNC/NCO-NF/graphite electrode) exhibited excellent non-enzymatic glucose detection over a wide range of concentration with a lower limit of 1.2 ?M and sensitivity of 1827.5 ?A mM?1 mg?1 in 0.1 M NaOH. Further, the modified electrodes were also tuned for H2O2 detection to aid enzymatic glucose sensing. When examined for bifunctional water-splitting in 1 M NaOH, the electrode reached an onset potential of ?0.537 V and 0.735 V against reversible hydrogen reference electrode and a Tafel slope of 37.6 mV dec?1 and 67.0 mV dec?1 for hydrogen and oxygen evolution reactions, respectively. The results prove that GNC/NCO-NF are promising candidates as multifunctional electrocatalyst. 2019 Elsevier Ltd and Techna Group S.r.l.
Graphene nanoclusters embedded nickel cobaltite nanofibers as multifunctional electrocatalyst for glucose sensing and water-splitting applications
(Elsevier Ltd, 2019) Kumar, B.S.; Gudla, V.C.; Ambat, R.; Kalpathy, S.K.; Anandhan, S.
Nickel cobaltite (NCO) attains the apex of Sabatier-type volcano plot for electrochemical reaction compared to simple oxides due to synergetic effect of mixed transition metal cations. The combination of high surface area, aspect ratio, and porosity of electrospun NCO nanofibers (NCO-NF) enhance their electrocatalytic performance by improved electron mobility and more active sites. In the present study, NCO-NF fabricated using poly (styrene-co-acrylonitrile) (SAN) as a sacrificial polymer, were embellished with graphene nanoclusters (GNC), which augment the electrocatalytic performance of the NCO-NF. The in situ formed GNC along the NCO-NF are result of the interaction between the polar functional groups of the polymer, and the cations of precursor salts during the calcination of precursor nanofibers. The GNC/NCO-NF with least crystallite size and high aspect ratio having porous NCO nanoparticles and in situ grown GNC were developed using sol-gel electrospinning process assisted by calcination of precursor nanofibers. This simple, eco-friendly, and economical synthesis route with unique structure chemistry of SAN to form GNC and the presence of dual cations (Ni and Co) provides enhanced performance and multifunctionality to GNC/NCO-NF electrodes for electrocatalytic applications, such as biosensors and water-splitting. In the present study, the modified electrodes (GNC/NCO-NF/graphite electrode) exhibited excellent non-enzymatic glucose detection over a wide range of concentration with a lower limit of 1.2 ?M and sensitivity of 1827.5 ?A mM?1 mg?1 in 0.1 M NaOH. Further, the modified electrodes were also tuned for H2O2 detection to aid enzymatic glucose sensing. When examined for bifunctional water-splitting in 1 M NaOH, the electrode reached an onset potential of ?0.537 V and 0.735 V against reversible hydrogen reference electrode and a Tafel slope of 37.6 mV·dec?1 and 67.0 mV·dec?1 for hydrogen and oxygen evolution reactions, respectively. The results prove that GNC/NCO-NF are promising candidates as multifunctional electrocatalyst. © 2019 Elsevier Ltd and Techna Group S.r.l.
Performance and Reliability Codesign for Superjunction Drain Extended MOS Devices
(2017) Somayaji, J.; Kumar, B.S.; Bhat, M.S.; Shrivastava, M.
Conventionally, integrated drain-extended MOS (DeMOS) like high-voltage devices are designed while keeping only performance targets for a given application in mind. In this paper, for the first time, performance and reliability codesign approach using 3-D TCAD has been presented for various superjunction (SJ) type DeMOS devices. In this context, how to effectively utilize the SJ concept in a DeMOS device for System on Chip applications, which often has stringent switching and RF performance targets, is explored in detail in this paper. Moreover, design and reliability tradeoffs for switching and RF applications are discussed, while considering two unique sets, one with fixed breakdown voltage and other with fixed ON-resistance. Finally, hot carrier generation, safe operating area concerns, and electrostatic discharge physics are explored and compared using 3-D TCAD simulations. 1963-2012 IEEE.
Performance and Reliability Codesign for Superjunction Drain Extended MOS Devices
(Institute of Electrical and Electronics Engineers Inc., 2017) Somayaji, J.; Kumar, B.S.; Bhat, M.S.; Shrivastava, M.
Conventionally, integrated drain-extended MOS (DeMOS) like high-voltage devices are designed while keeping only performance targets for a given application in mind. In this paper, for the first time, performance and reliability codesign approach using 3-D TCAD has been presented for various superjunction (SJ) type DeMOS devices. In this context, how to effectively utilize the SJ concept in a DeMOS device for System on Chip applications, which often has stringent switching and RF performance targets, is explored in detail in this paper. Moreover, design and reliability tradeoffs for switching and RF applications are discussed, while considering two unique sets, one with fixed breakdown voltage and other with fixed ON-resistance. Finally, hot carrier generation, safe operating area concerns, and electrostatic discharge physics are explored and compared using 3-D TCAD simulations. © 1963-2012 IEEE.
Probing the influence of strontium doping and annealing temperature on the structure and biocompatibility of hydroxyapatite nanorods
(Royal Society of Chemistry, 2024) Patil, H.G.; Rajendran, A.; Lenka, N.; Kumar, B.S.; Murugesan, S.; Anandhan, S.
Among numerous biologically important metal cations, strontium (Sr2+) has received much attention in bone tissue regeneration because of its osteoinductive properties combined with its ability to inhibit osteoclast activity. In this study, strontium-doped hydroxyapatite (Sr-HAp) nanorods with varying molar ratios of Ca : Sr (10 : 0, 9 : 1, 5 : 5, 3 : 7 and 0 : 10) were synthesized using the chemical precipitation technique. The synthesized Sr-HAp nanostructures were characterized using powder X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy, energy dispersive X-ray spectroscopy, and Raman and Fourier transform infrared (FTIR) spectroscopies to understand their structural and morphological features, and composition. XRD results revealed the formation of HAp nanostructures, whose unit cell volume increased as a function of the dopant level. The reaction process investigation showed the formation of hydroxyapatite (HAp), strontium apatite (SAp) and various Sr-HAp phases. FESEM micrographs displayed the morphological transformation of Sr-HAp from nanorods to nanosheets upon increasing the dopant level. In the FTIR spectra, the bands of the PO43− group shifted towards a lower wavenumber upon increasing the dopant concentration in Sr-HAp that signifies the structural distortion due to the presence of a large amount of strontium ions. The peaks of PO43− and OH− vibrations in the Raman spectra were further analysed to corroborate the structural distortion of Sr-HAp. Selected area electron diffraction patterns obtained using TEM reveal the reduced crystallinity of Sr-HAp due to Sr-doping, which is in line with the XRD results. Finally, the MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay showed that the synthesized Sr-HAp has no toxic effect on the survival and growth of mesenchymal stem cells. In summary, the synthesized novel Sr-HAp nanorods exhibit great promise for bone tissue engineering applications. © 2024 The Royal Society of Chemistry.
Pyrolysis-controlled synthesis and magnetic properties of sol gel electrospun nickel cobaltite nanostructures
(2018) Kumar, B.S.; Dhanasekhar, C.; Venimadhav, A.; Kalpathy, S.K.; Anandhan, S.
Nickel cobaltite (NCO) is a binary transition-metal oxide, which is extensively used as an electrocatalyst and magnetic material. NCO nanofibers and NCO/graphene composite exhibit high electrochemical reactivity due to the directional bridging of NCO particles. This makes NCO a promising candidate electrode material for use in supercapacitors and batteries. Besides, NCO is also a promising magnetic material due to its unique structural composition, where the cations are seated in octahedral sites surrounded by oxygen vacancies. In the present work, a simple and reliable method was discovered for tuning the morphological and structural changes of nickel cobaltite (NCO) nanoparticles, which were reshaped along the NCO nanofibers, by controlling the pyrolysis soaking time. As the pyrolysis soaking time increases, NCO transforms from inverse spinel to normal spinel; and the morphology of NCO nanoparticles changes from spherical to rod-like. These changes were validated by the hypsochromic peak shifts in Raman, and FTIR spectroscopies. The magnetic measurements reveal changes in the shape of the hysteresis loop, which are explained on the basis of structural and morphological changes in the nanostructure. The net magnetisation increases and coercivity decreases, with an increase in pyrolysis soaking time. These changes in magnetic parameters are attributed to structural changes caused by the formation of oxygen vacancies, and surface effects due to switching in morphology of the NCO nanoparticle. [Figure not available: see fulltext.]. 2018, Springer Science+Business Media, LLC, part of Springer Nature.
Pyrolysis-controlled synthesis and magnetic properties of sol–gel electrospun nickel cobaltite nanostructures
(Springer New York LLC barbara.b.bertram@gsk.com, 2018) Kumar, B.S.; Dhanasekhar, C.; Adyam, A.; Kalpathy, S.K.; Anandhan, S.
Nickel cobaltite (NCO) is a binary transition-metal oxide, which is extensively used as an electrocatalyst and magnetic material. NCO nanofibers and NCO/graphene composite exhibit high electrochemical reactivity due to the directional bridging of NCO particles. This makes NCO a promising candidate electrode material for use in supercapacitors and batteries. Besides, NCO is also a promising magnetic material due to its unique structural composition, where the cations are seated in octahedral sites surrounded by oxygen vacancies. In the present work, a simple and reliable method was discovered for tuning the morphological and structural changes of nickel cobaltite (NCO) nanoparticles, which were reshaped along the NCO nanofibers, by controlling the pyrolysis soaking time. As the pyrolysis soaking time increases, NCO transforms from inverse spinel to normal spinel; and the morphology of NCO nanoparticles changes from spherical to rod-like. These changes were validated by the hypsochromic peak shifts in Raman, and FTIR spectroscopies. The magnetic measurements reveal changes in the shape of the hysteresis loop, which are explained on the basis of structural and morphological changes in the nanostructure. The net magnetisation increases and coercivity decreases, with an increase in pyrolysis soaking time. These changes in magnetic parameters are attributed to structural changes caused by the formation of oxygen vacancies, and surface effects due to switching in morphology of the NCO nanoparticle. [Figure not available: see fulltext.]. © 2018, Springer Science+Business Media, LLC, part of Springer Nature.
Sol gel electrospun mesoporous ZnMn2O4 nanofibers with superior specific surface area
(2017) Shamitha, C.; Senthil, T.; Wu, L.; Kumar, B.S.; Anandhan, S.
ZnMn2O4 has application potential in lithium ion batteries, supercapacitors, sensors, and thermistors. In this study, mesoporous spinel ZnMn2O4 nanofibers were synthesized by sol gel assisted electrospinning combined with calcination, using poly(styrene-co-acrylonitrile) as sacrificial polymeric binder. Structural, morphological and optical properties of these ceramic nanofibers were characterized. X-ray diffraction and X-ray photoelectron spectroscopy results revealed the presence of hexagonal ZnMnO3 and MnO phases in the ZnMn2O4 nanofibers produced. Based on these observations we propose a plausible mechanism of formation of ZnMn2O4 nanofibers. The nanofibers calcined at 773 K exhibit a specific surface area of 79.5 m2 g?1, which is higher than that of the zinc manganite nanofibers synthesized hitherto by sol gel electrospinning. Moreover, this material exhibits four bandgaps, which is believed to be the first observation in ZnMn2O4 nanofibers. 2017, Springer Science+Business Media, LLC.
Some new observations on the structural and phase evolution of nickel titanate nanofibers
(2017) Kumar, B.S.; Shanmugharaj, A.M.; Kalpathy, S.K.; Anandhan, S.
In this study, we report for the first time the synthesis of nickel titanate (NTO) nanofibers containing a mixture of ilmenite and spinel phases of NTO, at an atypical low temperature. Precursor nanofibers produced by sol-gel electrospinning were calcined at three different temperatures to produce the NTO nanofibers. Thermal analysis along with X-ray photoelectron spectroscopy confirmed the formation of non-crystalline stable phases of TiN and Ti-O-N that restrained the formation of ilmenite NTO, and the Ni-rich environment pushed the Ti atoms to tetrahedral sites to form a defective spinel structure. The crystallite size of spinel NTO was observed to increase as a function of the calcination temperature above 700 C, as the activation energy for coalescence and growth of spinel NTO was favorable. NTO nanofibers obtained above the calcination temperature of 700 C exhibited new band gap energy around 2.5 eV in Tauc plot. Oxygen vacancies in these ceramic nanofibers decreased as the calcination temperature was increased. A hypsochromic shift of 20 nm in the photoluminescence spectra suggested that the material had a Ni2+ rich NTO (spinel). 2017 Elsevier Ltd and Techna Group S.r.l.
Some new observations on the structural and phase evolution of nickel titanate nanofibers
(Elsevier Ltd, 2017) Kumar, B.S.; Shanmugharaj, A.M.; Kalpathy, S.K.; Anandhan, S.
In this study, we report for the first time the synthesis of nickel titanate (NTO) nanofibers containing a mixture of ilmenite and spinel phases of NTO, at an atypical low temperature. Precursor nanofibers produced by sol-gel electrospinning were calcined at three different temperatures to produce the NTO nanofibers. Thermal analysis along with X-ray photoelectron spectroscopy confirmed the formation of non-crystalline stable phases of TiN and Ti-O-N that restrained the formation of ilmenite NTO, and the Ni-rich environment pushed the Ti atoms to tetrahedral sites to form a defective spinel structure. The crystallite size of spinel NTO was observed to increase as a function of the calcination temperature above 700 °C, as the activation energy for coalescence and growth of spinel NTO was favorable. NTO nanofibers obtained above the calcination temperature of 700 °C exhibited new band gap energy around 2.5 eV in Tauc plot. Oxygen vacancies in these ceramic nanofibers decreased as the calcination temperature was increased. A hypsochromic shift of 20 nm in the photoluminescence spectra suggested that the material had a Ni2+ rich NTO (spinel). © 2017 Elsevier Ltd and Techna Group S.r.l.