Browsing by Author "J, J."

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    A review on NLP zero-shot and few-shot learning: methods and applications
    (Springer Nature, 2025) Ramesh, G.; Sahil, M.; Palan, S.A.; Bhandary, D.; Ashok, T.A.; J, J.; Sowjanya, N.
    Zero-shot and few-shot learning techniques in natural language processing (NLP), this comprehensive review traces their evolution from traditional methods to cutting-edge approaches like transfer learning and pre-trained language models, semantic embedding, attribute-based approaches, generative models for data augmentation in zero-shot learning, and meta-learning, model-agnostic meta-learning, relationship networks, model-agnostic meta-learning (MAML), prototypical networks in few-shot learning. Real-world applications underscore the adaptability and efficacy of these techniques across various NLP tasks in both industry and academia. Acknowledging challenges inherent in zero-shot and few-shot learning, this review identifies limitations and suggests avenues for improvement. It emphasizes theoretical foundations alongside practical considerations such as accuracy and generalization across diverse NLP tasks. By consolidating key insights, this review provides researchers and practitioners with valuable guidance on the current state and future potential of zero-shot and few-shot learning techniques in addressing real-world NLP challenges. Looking ahead, this review aims to stimulate further research, fostering a deeper understanding of the complexities and applicability of zero-shot and few-shot learning techniques in NLP. By offering a roadmap for future exploration, it seeks to contribute to the ongoing advancement and practical implementation of NLP technologies across various domains. © The Author(s) 2025.
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    Combustion-derived BaNiO3 nanoparticles as a potential bifunctional electrocatalyst for overall water splitting
    (Elsevier Ltd, 2023) J, J.; Jayalakshmi, D.; Rodney, J.D.
    Electrochemical water electrolyser though an assuring solution for clean hydrogen production, the sluggish kinetics and high cost of existing precious metal electrocatalyst remains a barrier to its effective utilization. Herein, solution combustion route derived perovskite type barium nickelate (BaNiO3) nanoparticles were developed and studied for their bifunctional electrocatalytic properties towards overall water splitting. The unannealed BaNiO3 nanoparticles exhibited the highest OER and HER activity with overpotentials 253 mV and 427 mV respectively to attain 10 mAcm−2 in 1.0 M KOH. Using unannealed BaNiO3 as a bifunctional electrocatalyst in a two-electrode alkaline electrolyser, the cell was able to achieve the benchmark current density at a low cell voltage of 1.82 V. Impressively the setup's electrocatalytic performance improved 4.9% after continuous overall water splitting for 24 h at 30 mAcm−2. Therefore, BaNiO3 nanoparticles can be a low-cost and efficient alternative for noble metal electrocatalysts for clean H2 production. © 2022 Hydrogen Energy Publications LLC
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    Effect of annealing temperature on the bifunctional electrocatalytic properties of strontium nickelate (SrNiO3) nanoparticles for efficient overall water splitting
    (Elsevier Ltd, 2022) J, J.; Jayalakshmi, J.; Rodney, J.D.
    The global trend in energy demand has paved way for clean hydrogen (H2) energy production at large scale. To address this issue, perovskite (ABX3) nanomaterials are widely researched to replace the noble metal electrocatalysts for electrochemical water splitting. In this work, the effect of annealing temperature on the structural and electrochemical properties of combustion derived strontium nickelate (SrNiO3) nanoparticles are studied. Benefitting from the unique features of perovskites, SrNiO3 nanoparticles displays excellent OER and HER activity in 1.0 M KOH with an overpotential of 259 mV and 451 mV to achieve 10 mAcm−2 respectively. SrNiO3 nanoparticles show superior HER activity when annealed at higher temperature and subtle change in OER activity. The stability of SrNiO3 nanoparticles were noteworthy as it shows no degradation even after 12 h. The overall water splitting of highly active SrNiO3 nanoparticles was carried out in a two-electrode system and the setup posted a cell voltage of 1.88 V at 10 mAcm−2 after continuous water splitting for 24 h. Thus, SrNiO3 nanoparticles may possibly serve as a potential bifunctional electrocatalyst for H2 production. © 2022 Hydrogen Energy Publications LLC
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    Sustained hydrogen production through alkaline water electrolysis using Bridgman–Stockbarger derived indium-impregnated copper chromium selenospinel
    (Elsevier Ltd, 2024) Jauhar, R.M.; Raji, R.; Deepapriya, S.; Raja, A.; Rao, L.; Joshi, S.; Era, P.; Badekai Ramachandra, B.R.; Udayashankar, N.K.; Vadivel, V.; Mangalaraja, R.V.; J, J.; Ghfar, A.A.; Senthilpandian, M.; Kim, B.C.; Rodney, J.D.
    The depletion of conventional fossil fuels necessitates the development of sustainable energy alternatives, with electrochemical water splitting for hydrogen (H2) production being a promising solution. However, large-scale hydrogen generation is hindered by the scarcity of cost-effective electrocatalysts to replace noble metals such as Pt and RuO2 in the Oxygen Evolution Reaction (OER) and Hydrogen Evolution Reaction (HER). In this study, we report the synthesis of CuCr2-xInxSe4 (x = 0, 0.2, 0.4) using a dual approach combining the Bridgman-Stockbarger method and ball milling. Among the synthesized materials, CuCr1.8In0.2Se4 demonstrates outstanding HER activity in 1.0 M KOH, achieving a potential of ?0.16 V vs. RHE at a current density of 10 mA cm?2. Moreover, the material shows remarkable durability during a three-electrode accelerated degradation test in an alkaline medium, maintaining its performance over 24 h at a constant current density of ?200 mA cm?2, with a stable potential of ?0.57 V vs. RHE. Additionally, CuCr1.8In0.2Se4 was tested in a two-electrode configuration alongside CoFe LDH, achieving a benchmark of 1.7 V for overall water splitting. It sustained a current density of 400 mA cm?2 for 24 h in an accelerated degradation test, exhibiting a minimal loss of 0.1 V after the testing period. These results highlight CuCr1.8In0.2Se4 as a promising non-noble metal catalyst for HER, demonstrating its potential to reduce reliance on noble materials for large-scale hydrogen production. © 2024 Hydrogen Energy Publications LLC