Browsing by Author "Ghosh, S."

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A high thermally stable polyacrylonitrile (PAN)-based gel polymer electrolyte for rechargeable Mg-ion battery
(Springer, 2020) Singh, R.; Janakiraman, S.; Khalifa, M.; Anandhan, S.; Ghosh, S.; Adyam, A.; Biswas, K.
The ionic conductivity and thermal stability of the electrolyte-separator system is an essential parameter for improving battery performance and safety. The present work addresses the high thermally stable gel polymer electrolyte (GPE) using polyacrylonitrile (PAN) as a polymer membrane and magnesium perchlorate in propylene carbonate (Mg(ClO4)2-PC) as a liquid electrolyte. The PAN based polymer membrane is prepared by electrospinning process which produces a bead free and uniformly distributed nanofibers. The electrospun PAN based GPE is characterized by different physical and electrochemical techniques like X-ray diffraction, field emission scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, ionic conductivity, linear sweep voltammetry, magnesium ion transference number and electrochemical impedance spectroscopy. The ionic conductivity of PAN is 3.28 mS cm?1, compared to that of PP Celgard is 1.97 × 10–4 mS cm?1 at 30 °C. The electrochemical stability of PAN is 4.6 V and also exhibits excellent interfacial stability with magnesium metal. The results showed that the PAN-based GPE has higher ionic conductivity and thermal stability than the polypropylene (PP) Celgard membrane. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.
A new strategy of PVDF based Li-salt polymer electrolyte through electrospinning for lithium battery application
(Institute of Physics Publishing helen.craven@iop.org, 2019) Janakiraman, S.; Surendran, A.; Ghosh, S.; Anandhan, S.; Adyam, A.
Polyvinylidene fluoride (PVDF) ultrafine fibers with different proportions of lithium nitrate (LiNO3) were fabricated by an electrospinning device. The processing parameters are optimized to 19 wt% PVDF to get a bead free structure. Scanning electron microscope (SEM) and atomic force microscope (AFM) showed the uniform and interconnected porous structure. With the addition of 2 wt% LiNO3, the fiber diameter of the electrospun membrane decreased from 371 to 222 nm. Furthermore, the addition of LiNO3 into the nanofibrous membrane enhanced the ionic conductivity from 0.97 ×10-3 S cm-1 to 1.61 ×10-3 S cm-1 at room temperature after soaking with 1 M LiPF6 (lithium hexafluoro-phosphate) in ethylene carbonate (EC) and diethyl carbonate (DEC) in (1:1 wt%). Compared with the conventional Celgard and pristine PVDF membrane, the salt doped PVDF membranes showed higher electrochemical stability window and lower interfacial resistance. The electrospun membrane separators (ES) were assembled into Lithium cobalt oxide (LiCoO2) as cathode and lithium metal as an anode. The salt doped membrane showed superior discharge, C-rate and stable cycle performance than the commercial Celgard membrane. © 2018 IOP Publishing Ltd.
A Novel Orbirect Inductive Coil Structure for Wireless Inductive Power Transfer in Electric Vehicle Battery Charging Applications
(IEEE Computer Society, 2025) Kishan, D.; Ghosh, S.; Chauhan, S.; Chub, A.
Wireless battery charging systems for electric vehicles (EVs) are convenient, safe, and flexible against environmental hazards. Resonant inductive power transfer (RIPT) is the most common method for EV battery charging applications. The inductive coil structure is a major component of the RIPT system, and misalignment between inductive coils is a key issue. This paper proposes an improved, misalignment-tolerant, novel dual orbirect inductive coil structure. The proposed coil structure is designed using finite element modeling (FEM) and investigates magnetic parameters such as self and mutual inductance at various horizontal and vertical misalignment distances. Finally, based on the FEM analysis, the RIPT system is designed for 1 kW, and simulations were carried out in MATLAB. The presented results show that the output voltage exhibits minimal variation across 50% misalignment range. The peak efficiency achieved at full load conditions is 96.2%. Â© 2025 IEEE.
An electroactive ?-phase polyvinylidene fluoride as gel polymer electrolyte for magnesium–ion battery application
(Elsevier B.V., 2019) Singh, R.; Janakiraman, S.; Khalifa, M.; Anandhan, S.; Ghosh, S.; Adyam, A.; Biswas, K.
The gel polymer electrolytes (GPEs) are currently interesting research area in rechargeable batteries. In the present study, synthesis and characterization of electroactive gel polymer electrolyte (EGPE) for Mg-ion batteries application have been investigated. The bead free electroactive polyvinylidene fluoride (PVDF) with high porosity is achieved by an electrospinning process. The ?-phase of PVDF is polar and electroactive with a high dipole moment. Electroactive ?-phase is confirmed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). Field emission scanning electron microscopy (FESEM) study is done to analyze the structure and morphology of the electroactive membrane. The electroactive gel polymer electrolyte is formed by immersing an electroactive PVDF membrane in 0.3 M magnesium perchlorate (MgClO4) and propylene carbonate (PC) solution. The ionic conductivity of electroactive ?-phase PVDF membrane is achieved to be 1.49 mS cm?1 at 30 °C, which is higher than commercial available polypropylene (PP) Celgard. Tortuosity of electroactive gel polymer electrolyte is found to be 1.44. The voltage stability of the EGPE is stable up to a high voltage of 5.0 V against Mg+2/Mg. The total ionic transference number and magnesium ion transference number of EGPE are also investigated to confirm high ionic conductivity. © 2019 Elsevier B.V.
Comparative Studies on Crystalline and Amorphous Vinylidene Fluoride Based Fibrous Polymer Electrolytes for Sodium-Ion Batteries
(Springer Singapore, 2020) Janakiraman, S.; Khalifa, M.; Biswal, R.; Ghosh, S.; Anandhan, S.; Adyam, A.
In the present work, electrospun poly (vinylidene fluoride) (PVDF) and poly (vinylidene fluoride-co hexafluropropylene) (P(VdF-co-HFP)) fibrous membranes have been compared. Porous homo and copolymer fiber-based membranes with an interconnected structure, high porosity, large electrolyte uptake were prepared by an electrospinning route. The effect of crystallinity in terms of X-ray diffraction (XRD) was investigated for the fibrous polymer membranes (FPMs). The surface morphology of the FPMs is evaluated by field emission scanning electronmicroscopy (FESEM). The FPMswere soaked in 1MNaClO4-ethylene carbonate (EC)/diethyl carbonate (DEC) (1:1, vol%) solution to form fibrous polymer electrolytes (FPEs). The ionic conductivity of copolymer showed 1.126 mS cm−1 under ambient temperature (at 28 °C) higher than the homopolymer (0.79 mS cm−1) because of HFP unit. The electrochemical stability window of the copolymer membrane also enhanced and stable up to 4.9 V versus Na+/Na suitable for high voltage sodium rechargeable batteries. When tested with Na066Fe0.5Mn05O2 as cathode and Na metal as an anode, the cycle performance significantly improved for the copolymer. © Springer Nature Singapore Pte Ltd. 2021.
An electroactive ?-phase polyvinylidene fluoride as gel polymer electrolyte for magnesium ion battery application
(2019) Singh, R.; Janakiraman, S.; Khalifa, M.; Anandhan, S.; Ghosh, S.; Venimadhav, A.; Biswas, K.
The gel polymer electrolytes (GPEs) are currently interesting research area in rechargeable batteries. In the present study, synthesis and characterization of electroactive gel polymer electrolyte (EGPE) for Mg-ion batteries application have been investigated. The bead free electroactive polyvinylidene fluoride (PVDF) with high porosity is achieved by an electrospinning process. The ?-phase of PVDF is polar and electroactive with a high dipole moment. Electroactive ?-phase is confirmed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). Field emission scanning electron microscopy (FESEM) study is done to analyze the structure and morphology of the electroactive membrane. The electroactive gel polymer electrolyte is formed by immersing an electroactive PVDF membrane in 0.3 M magnesium perchlorate (MgClO4) and propylene carbonate (PC) solution. The ionic conductivity of electroactive ?-phase PVDF membrane is achieved to be 1.49 mS cm?1 at 30 C, which is higher than commercial available polypropylene (PP) Celgard. Tortuosity of electroactive gel polymer electrolyte is found to be 1.44. The voltage stability of the EGPE is stable up to a high voltage of 5.0 V against Mg+2/Mg. The total ionic transference number and magnesium ion transference number of EGPE are also investigated to confirm high ionic conductivity. 2019 Elsevier B.V.
Electroactive poly(vinylidene fluoride) fluoride separator for sodium ion battery with high coulombic efficiency
(2016) Janakiraman, S.; Surendran, A.; Ghosh, S.; Anandhan, S.; Venimadhav, A.
Electroactive separators are recent interest in self-charging rechargeable batteries. In this study, electrospun polyvinylidene fluoride (PVDF) is characterized as an electroactive separator for Na-ion batteries. The intrinsic ?-phase with high porosity of the separator is confirmed from X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM) and Atomic Force Microscopy (AFM) studies. The electroactive separator is immersed in 1M NaClO4-ethylene carbonate (EC)/diethyl carbonate (DEC) (1:1 by weight) solution. The physicochemical characteristics of electroactive separator electrolyte (EaSE) were investigated using sodium ion conductivity, ion transference number and contact angle measurements. Linear and cyclic voltammetry studies were also carried out for the electrolyte system to evaluate oxidation stability window. The inherent ?-phases of the separator as obtained by electrospinning has an ionic conductivity of ~ 7.38 10- 4 S cm- 1 under ambient condition. Sodium ion cell made from EaSE with Na0 66Fe0.5Mn0 5O2 as cathode and Na metal as anode has displayed a stable cycle performance with a coulombic efficiency of 92% after 90 cycles. 2016 Published by Elsevier B.V.
Electroactive poly(vinylidene fluoride) fluoride separator for sodium ion battery with high coulombic efficiency
(Elsevier B.V., 2016) Janakiraman, S.; Surendran, A.; Ghosh, S.; Anandhan, S.; Adyam, A.
Electroactive separators are recent interest in self-charging rechargeable batteries. In this study, electrospun polyvinylidene fluoride (PVDF) is characterized as an electroactive separator for Na-ion batteries. The intrinsic ?-phase with high porosity of the separator is confirmed from X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM) and Atomic Force Microscopy (AFM) studies. The electroactive separator is immersed in 1M NaClO4-ethylene carbonate (EC)/diethyl carbonate (DEC) (1:1 by weight) solution. The physicochemical characteristics of electroactive separator electrolyte (EaSE) were investigated using sodium ion conductivity, ion transference number and contact angle measurements. Linear and cyclic voltammetry studies were also carried out for the electrolyte system to evaluate oxidation stability window. The inherent ?-phases of the separator as obtained by electrospinning has an ionic conductivity of ~ 7.38 × 10- 4 S cm- 1 under ambient condition. Sodium ion cell made from EaSE with Na0·66Fe0.5Mn0·5O2 as cathode and Na metal as anode has displayed a stable cycle performance with a coulombic efficiency of 92% after 90 cycles. © 2016 Published by Elsevier B.V.
Electrochemical characterization of a polar ?-phase poly (vinylidene fluoride) gel electrolyte in sodium ion cell
(2019) Janakiraman, S.; Surendran, A.; Biswal, R.; Ghosh, S.; Anandhan, S.; Venimadhav, A.
A polar ?-phase poly (vinylidene fluoride) (PVDF) membrane is developed through the electrospinning method. PVDF gel electrolyte for sodium ion batteries was obtained by saturating the bare porous membrane in a liquid electrolyte, 1 M NaClO4 in EC: DEC (1:1 vol%). The physical and electrochemical characteristics of the polar ?-phase PVDF membrane are explored by X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Atomic force microscope (AFM), sodium ion conductivity, linear sweep voltammetry (LSV) and sodium ion transference number. The ionic conductivity of a polar ?-phase PVDF gel electrolyte exhibited 9.2 10?4 S cm?1, higher than the commercially used Celgard 2400 membrane 0.36 10?4 S cm?1 at ambient temperature. The electrochemical expolarations of the sodium ion half-cell (Na2/3Fe1/2Mn1/2O2) as a cathode and sodium metal as a counter electrode) conducted from PVDF gel electrolyte are analysed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV of the battery showed a pseudo capacitive nature. The equivalent circuit model of the sodium ion cell brought out the effect of dipole moments in the polymer chains on the battery performance. 2018 Elsevier B.V.
Electrochemical characterization of a polar ?-phase poly (vinylidene fluoride) gel electrolyte in sodium ion cell
(Elsevier B.V., 2019) Janakiraman, S.; Surendran, A.; Biswal, R.; Ghosh, S.; Anandhan, S.; Adyam, A.
A polar ?-phase poly (vinylidene fluoride) (PVDF) membrane is developed through the electrospinning method. PVDF gel electrolyte for sodium ion batteries was obtained by saturating the bare porous membrane in a liquid electrolyte, 1 M NaClO4 in EC: DEC (1:1 vol%). The physical and electrochemical characteristics of the polar ?-phase PVDF membrane are explored by X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Atomic force microscope (AFM), sodium ion conductivity, linear sweep voltammetry (LSV) and sodium ion transference number. The ionic conductivity of a polar ?-phase PVDF gel electrolyte exhibited 9.2 × 10?4 S cm?1, higher than the commercially used Celgard® 2400 membrane 0.36 × 10?4 S cm?1 at ambient temperature. The electrochemical expolarations of the sodium ion half-cell (Na2/3Fe1/2Mn1/2O2) as a cathode and sodium metal as a counter electrode) conducted from PVDF gel electrolyte are analysed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV of the battery showed a pseudo capacitive nature. The equivalent circuit model of the sodium ion cell brought out the effect of dipole moments in the polymer chains on the battery performance. © 2018 Elsevier B.V.
Electrospun electroactive polyvinylidene fluoride-based fibrous polymer electrolyte for sodium ion batteries
(2019) Janakiraman, S.; Surendran, A.; Biswal, R.; Ghosh, S.; Anandhan, S.; Venimadhav, A.
Electrospinning is an efficient technique to produce ultrafine electroactive mat, diameters ranging from few nanometers to micrometers to use as a separator in sodium ion battery. The polyvinylidene fluoride (PVDF) polymer solution was optimized to 19 wt%, applied voltage 25 kV and flow rate of 0.5 ml h-1 to get a bead free ultrafine electroactive structure. The electroactive ?-phase is confirmed by x-ray diffractometer (XRD). Ionic conductivities, electrolyte uptake, wettability, linear sweep voltammetry (LSV) and thermal stability of the electroactive fibrous polymer electrolyte (EFPE) were studied by soaking the separator with a liquid electrolyte of 1 M sodium hexafluorophosphate (NaPF6) dissolved in ethylene carbonate (EC)/propylene carbonate (PC) (1:1 vol%). The EFPE exhibits high ionic conductivity of 1.08 mS cm-1 and electrochemical stability window of 5.0 V versus Na/Na+ under ambient condition. The half-cell containing Na0.66Fe0.5Mn0.5O2 as cathode and EFPE as the separator cum electrolyte showed a stable cycling performance at a current rate of 0.1C. 2019 IOP Publishing Ltd.
Electrospun electroactive polyvinylidene fluoride-based fibrous polymer electrolyte for sodium ion batteries
(Institute of Physics Publishing helen.craven@iop.org, 2019) Janakiraman, S.; Surendran, A.; Biswal, R.; Ghosh, S.; Anandhan, S.; Adyam, A.
Electrospinning is an efficient technique to produce ultrafine electroactive mat, diameters ranging from few nanometers to micrometers to use as a separator in sodium ion battery. The polyvinylidene fluoride (PVDF) polymer solution was optimized to 19 wt%, applied voltage 25 kV and flow rate of 0.5 ml h-1 to get a bead free ultrafine electroactive structure. The electroactive ?-phase is confirmed by x-ray diffractometer (XRD). Ionic conductivities, electrolyte uptake, wettability, linear sweep voltammetry (LSV) and thermal stability of the electroactive fibrous polymer electrolyte (EFPE) were studied by soaking the separator with a liquid electrolyte of 1 M sodium hexafluorophosphate (NaPF6) dissolved in ethylene carbonate (EC)/propylene carbonate (PC) (1:1 vol%). The EFPE exhibits high ionic conductivity of 1.08 mS cm-1 and electrochemical stability window of 5.0 V versus Na/Na+ under ambient condition. The half-cell containing Na0.66Fe0.5Mn0.5O2 as cathode and EFPE as the separator cum electrolyte showed a stable cycling performance at a current rate of 0.1C. © 2019 IOP Publishing Ltd.
Ferromagnetism from non-magnetic ions: Ag-doped ZnO
(2019) Ali, N.; A., R, V.; Khan, Z.A.; Tarafder, K.; Kumar, A.; Wadhwa, M.K.; Singh, B.; Ghosh, S.
To develop suitable ferromagnetic oxides with Curie temperature (TC) at or above room temperature for spintronic applications, a great deal of research in doping ZnO with magnetic ions is being carried out over last decade. As the experimental results on magnetic ions doped ZnO are highly confused and controversial, we have investigated ferromagnetism in non-magnetic ion, Ag, doped ZnO. When Ag replaces Zn in ZnO, it adopts 4d9 configuration for Ag2+ which has single unpaired spin and suitable exchange interaction among these spins gives rise to ferromagnetism in ZnO with above room temperature TC. Experimentally, we have observed room temperature ferromagnetism (RTFM) in Ag-doped ZnO with Ag concentration varied from 0.03% to 10.0%. It is shown that zinc vacancy (VZn) enhances the ferromagnetic ordering (FMO) while oxygen vacancy (VO) retards the ferromagnetism in Ag-doped ZnO. Furthermore, the theoretical investigation revealed that VZn along with Ag2+ ions play a pivotal role for RTFM in Ag-doped ZnO. The Ag2+-Ag2+ interaction is ferromagnetic in the same Zn plane whereas anti-ferromagnetic in different Zn planes. The presence of VZn changes the anti-ferromagnetic to ferromagnetic state with a magnetic coupling energy of 37 meV. Finally, it has been established that the overlapping of bound magnetic polarons is responsible for RTFM in low doping concentration. However, anti-ferromagnetic coupling sets in at higher doping concentrations and hence weakens the FMO to a large extent. 2019, The Author(s).
Ferromagnetism from non-magnetic ions: Ag-doped ZnO
(Nature Research, 2019) Ali, N.; A R, V.; Khan, Z.A.; Tarafder, K.; Kumar, A.; Wadhwa, M.K.; Singh, B.; Ghosh, S.
To develop suitable ferromagnetic oxides with Curie temperature (TC) at or above room temperature for spintronic applications, a great deal of research in doping ZnO with magnetic ions is being carried out over last decade. As the experimental results on magnetic ions doped ZnO are highly confused and controversial, we have investigated ferromagnetism in non-magnetic ion, Ag, doped ZnO. When Ag replaces Zn in ZnO, it adopts 4d9 configuration for Ag2+ which has single unpaired spin and suitable exchange interaction among these spins gives rise to ferromagnetism in ZnO with above room temperature TC. Experimentally, we have observed room temperature ferromagnetism (RTFM) in Ag-doped ZnO with Ag concentration varied from 0.03% to 10.0%. It is shown that zinc vacancy (VZn) enhances the ferromagnetic ordering (FMO) while oxygen vacancy (VO) retards the ferromagnetism in Ag-doped ZnO. Furthermore, the theoretical investigation revealed that VZn along with Ag2+ ions play a pivotal role for RTFM in Ag-doped ZnO. The Ag2+-Ag2+ interaction is ferromagnetic in the same Zn plane whereas anti-ferromagnetic in different Zn planes. The presence of VZn changes the anti-ferromagnetic to ferromagnetic state with a magnetic coupling energy of 37 meV. Finally, it has been established that the overlapping of bound magnetic polarons is responsible for RTFM in low doping concentration. However, anti-ferromagnetic coupling sets in at higher doping concentrations and hence weakens the FMO to a large extent. © 2019, The Author(s).
Ferromagnetism in Mn-Doped ZnO: A Joint Theoretical and Experimental Study
(American Chemical Society, 2021) Ali, N.; Singh, B.; A R, V.; Lal, S.; Yadav, C.S.; Tarafder, K.; Ghosh, S.
We present a joint theoretical and experimental investigation on the origin of ferromagnetism in Mn-doped ZnO. Theoretical calculations revealed that the zinc vacancy (VZn) induces ferromagnetic ordering (FMO), whereas the oxygen vacancy (VO) quenches FMO in the Mn-doped ZnO system. This is further corroborated by the experimental results. Magnetic measurements revealed that Mn-doped ZnO shows room-temperature ferromagnetism (RTFM). Saturated magnetic moment per Mn2+ ion increases with oxygen partial pressure, indicating that the VZn enhances FMO in Mn-doped ZnO. Electron paramagnetic resonance and photoluminescence measurements revealed the presence of VZn in Mn-doped ZnO films. X-ray photoelectron spectroscopy measurements showed mixed oxidation states of Mn in Mn-doped ZnO films. Finally, we show that RTFM at very low doping concentrations is due to the overlapping of bound magnetic polarons. However, due to antiferromagnetic coupling at higher doping concentrations, the FMO weakens. © 2021 American Chemical Society.
Graphene Straintronics by Molecular Trapping
(American Chemical Society, 2025) Srivastava, P.K.; Khandelwal, V.; Reddy, I.R.; Tarafder, K.; Ghosh, S.
Here, we report on controlling strain in graphene by trapping molecules at the graphene–substrate interface and leveraging molecular dipole moments. Spectroscopic and transport measurements reveal that strain correlates with the dipole moments of trapped molecules extending beyond their molecular sizes, where values ranging from 1.5 to 4.9D lead to a 50-fold increase in strain and a significant rise in residual carrier density. This has been possible by charge transfer between graphene and trapped molecules, altering the C?C bond length and causing biaxial strain. First-principles density functional theory calculations confirm a consistent dependence of the bending height on molecular dipole moments. © 2025 American Chemical Society
Implementation of Acoustic Emission Testing to Study the Type of Cracking in Reinforced Concrete Beams
(Springer Science and Business Media Deutschland GmbH, 2021) Ghosh, S.; Agrawal, R.; Vidya Sagar, R.
In this experimental study, crack classification in reinforced concrete (RC) beams was carried out using acoustic emission (AE) testing. Two types of under reinforced RC beams were tested in laboratory subjected to four-point bending, and monotonically increased load was applied. The first type of RC beam had shear reinforcement (steel stirrups), and the second type of RC beam had no shear reinforcement. The generated AE during the fracture process in the tested RC beams were used for the crack classification analysis. Gaussian mixture modeling (GMM) of acoustic emission signals was performed. It was observed that the RC beam without shear reinforcement failed suddenly (brittle nature). However, the RC beam with shear reinforcement failed gradually thereby exhibiting ductile nature. In both theÂ RC beams, considerable AE related to shear cracking appeared at a 20â€“30% peak load. In the case of the RC beam with shear reinforcement, initially, tensile cracks were developed at the bottom of the beam and slowly started widening upward. Diagonal shear cracks started forming near to the supports when the test specimen reaching to collapse. In the case of the RC beam with no shear stirrups, tensile cracks originated at the bottom of the beam. But in this case, the influence of shear cracks developed near to the supports was more pronounced as it propagated rapidly. By comparing the different AE parameters, a steady increase in the number of hits till failure was observed in the case of the RC beam with shear reinforcement. But on the other hand, an abrupt increase in the number of hits was observed after 50% of peak load in the case of the RC beam with no shear reinforcement. The results are useful to study the sensitivity of AE to the shear reinforcement present in the RC beams. Â© 2021, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
Influence of Fiber Content on Acoustic Emission Characteristics Related to Steel Fiber-Reinforced Concrete Subjected to Unconfined Uniaxial Compression
(American Society of Civil Engineers (ASCE), 2021) Vidya Sagar, R.; Ghosh, S.; Kalloli, P.J.; Singh, M.
This article reports the experimental study of the influence of the fiber volume content in steel fiber-reinforced concrete (SFRC) on the acoustic emission (AE) characteristics. Plain concrete and SFRC specimens with various steel fiber contents were tested under unconfined uniaxial compression in the laboratory. Both AE testing and ultrasonic pulse velocity (UPV) methods were used to study the fracture process in the specimens. During the fracture process, the generated AE and axial compressive strain were recorded. The differences in AE characteristics of plain concrete and SFRC specimens were discussed. An absence of a considerable amount of AE for a certain period was observed (silent period of AE) near the peak load for SFRC specimens. The AE-based b-value suddenly decreased near the peak load during the fracture process in plain concrete. However, in the case of SFRC specimens, a sudden decrease near the peak load was not observed, and the b-value decreased gradually until failure, at which point it attained its minimum value. More AE related to shear cracking was observed in the case of SFRC specimens. This was due to interlocking between steel fibers, cement matrix, and coarse aggregates. AE testing is useful for studying the material characterization of SFRC, and is beneficial for assessing damage in structures constructed with SFRC. © 2021 American Society of Civil Engineers.
Modelling the land use system process for a pre-industrial landscape in India
(Springer Science and Business Media Deutschland GmbH, 2017) Ghosh, S.; Shetty, A.
Land in India is changing in a rapid pace since the green revolution during 1960 and industrial policy reforms during 1990. Certainly land cover land use (LCLU) changes have huge impacts on countries overall ecological balance and climate change. The most intriguing fact is LCLU change is an interconnected phenomenon like a system. The understanding of local level LCLU dynamics are yet to get a momentum in India. The present study is an attempt: (1) to examine the land use change drivers active at the studied landscape of coastal Karnataka in India and (2) to model the LCLU changes in pre-industrialized period using Dyna-CLUE model. Binary logistic regression was used to categorize land change drivers and to estimate the probability of changes. Odd ratio from logistic regression indicates that the biophysical drivers are most prominent in determining location of LCLU. They being slope, relative relief, drainage density and availability of ground water are the most influential drivers for most of the land classes. The Dyna-CLUE model is successful to simulate the LCLU change at aggregate level but the spatial allocation needs improvement. © 2017, Springer International Publishing Switzerland.
A new strategy of PVDF based Li-salt polymer electrolyte through electrospinning for lithium battery application
(2019) Janakiraman, S.; Surendran, A.; Ghosh, S.; Anandhan, S.; Venimadhav, A.
Polyvinylidene fluoride (PVDF) ultrafine fibers with different proportions of lithium nitrate (LiNO3) were fabricated by an electrospinning device. The processing parameters are optimized to 19 wt% PVDF to get a bead free structure. Scanning electron microscope (SEM) and atomic force microscope (AFM) showed the uniform and interconnected porous structure. With the addition of 2 wt% LiNO3, the fiber diameter of the electrospun membrane decreased from 371 to 222 nm. Furthermore, the addition of LiNO3 into the nanofibrous membrane enhanced the ionic conductivity from 0.97 10-3 S cm-1 to 1.61 10-3 S cm-1 at room temperature after soaking with 1 M LiPF6 (lithium hexafluoro-phosphate) in ethylene carbonate (EC) and diethyl carbonate (DEC) in (1:1 wt%). Compared with the conventional Celgard and pristine PVDF membrane, the salt doped PVDF membranes showed higher electrochemical stability window and lower interfacial resistance. The electrospun membrane separators (ES) were assembled into Lithium cobalt oxide (LiCoO2) as cathode and lithium metal as an anode. The salt doped membrane showed superior discharge, C-rate and stable cycle performance than the commercial Celgard membrane. 2018 IOP Publishing Ltd.