Browsing by Author "Daud, N.N.N."

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Adsorptive Treatment of Landfill Leachate using Activated Carbon Modified with Three Different Methods
(2018) Erabee, I.K.; Ahsan, A.; Jose, B.; Aziz, M.M.A.; Ng, A.W.M.; Idrus, S.; Daud, N.N.N.
Activated Carbon (AC) is an adsorbent having high surface area which makes the process of removing heavy metals from wastewater (such as landfill leachate) very effective. This study explored the utilization of three methods of modification of AC produced from coconut shell by treating it with nitric acid (HNO3), potassium permanganate (KMnO4) and heating at 600 C to improve the adsorption capacity. The AC can remove multi-pollutants in the filtration process which was used to treat landfill leachate. The water quality parameters such as pH, TSS, Ammonia-Nitrogen and a few heavy metals were considered in the present study. Results showed that the removal of these parameters was proportional with the increase of contact time and the bed depth of AC. The isotherm analysis of the adsorption of modified AC showed the best Removal Efficiency (RE) can be achieved when AC treated with KMnO4 for NH3-N, zinc, TSS and sulphide. The morphology of the AC was studied through Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectroscopy (EDX) pattern analysis and Fourier Transform Infrared (FTIR) analysis. It was found that various types of oxygen functional groups were introduced onto the surface of coconut shell derived AC through oxidation using HNO3. FTIR was used to characterize the surface oxygen functional groups. The surface functional groups such as N-H and C-H stretching played a significant role in heavy metals adsorption. Hence, it can be concluded that the hybrid technique by using electrolysis process with AC adsorption be an effective way to remove the suspended solids and heavy metals from landfill leachate and thus able to reduce environmental pollution. 2018, Korean Society of Civil Engineers.
Adsorptive Treatment of Landfill Leachate using Activated Carbon Modified with Three Different Methods
(Springer Verlag service@springer.de, 2018) Erabee, I.K.; Ahsan, A.; Jose, B.; Aziz, M.M.A.; Ng, A.W.M.; Idrus, S.; Daud, N.N.N.
Activated Carbon (AC) is an adsorbent having high surface area which makes the process of removing heavy metals from wastewater (such as landfill leachate) very effective. This study explored the utilization of three methods of modification of AC produced from coconut shell by treating it with nitric acid (HNO3), potassium permanganate (KMnO4) and heating at 600°C to improve the adsorption capacity. The AC can remove multi-pollutants in the filtration process which was used to treat landfill leachate. The water quality parameters such as pH, TSS, Ammonia-Nitrogen and a few heavy metals were considered in the present study. Results showed that the removal of these parameters was proportional with the increase of contact time and the bed depth of AC. The isotherm analysis of the adsorption of modified AC showed the best Removal Efficiency (RE) can be achieved when AC treated with KMnO4 for NH3-N, zinc, TSS and sulphide. The morphology of the AC was studied through Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectroscopy (EDX) pattern analysis and Fourier Transform Infrared (FTIR) analysis. It was found that various types of oxygen functional groups were introduced onto the surface of coconut shell derived AC through oxidation using HNO3. FTIR was used to characterize the surface oxygen functional groups. The surface functional groups such as N-H and C-H stretching played a significant role in heavy metals adsorption. Hence, it can be concluded that the hybrid technique by using electrolysis process with AC adsorption be an effective way to remove the suspended solids and heavy metals from landfill leachate and thus able to reduce environmental pollution. © 2018, Korean Society of Civil Engineers.
Effects of electric potential, NaCl, pH and distance between electrodes on efficiency of electrolysis in landfill leachate treatment
(2017) Erabee, I.K.; Ahsan, A.; Jose, B.; Arunkumar, T.; Sathyamurthy, R.; Idrus, S.; Daud, N.N.N.
This study investigated the effects of different parameters on the removal efficiencies of organic and inorganic pollutants in landfill leachate treatment by electrolysis. Different parameters were considered such as the electric potential (e.g., 24, 40 and 60 V), hydraulic retention time (HRT) (e.g., 40, 60, 80, 100 and 120 min), sodium chloride (NaCl) concentration (e.g., 1, 3, 5 and 7%), pH (e.g., 3, 7 and 9), electrodes materials [e.g., aluminum (Al) and iron (Fe)] and distance between electrodes (e.g., 1, 2 and 3 cm). The best operational condition of electrolysis was then recommended. The electric potential of 60 V with HRT of 120 min at 5% of NaCl solution using Al as anode and Fe as cathode (kept at a distance of 3 cm) was the most efficient condition which increased the removal efficiencies of various parameters such as turbidity, salinity, total suspended solids (TSS), total dissolved solids (TDS), biochemical oxygen demand (BOD), chemical oxygen demand (COD) and heavy metals (e.g., Zn and Mn). The higher removal percentages of many parameters, especially COD (94%) and Mn (93%) indicated that the electrolysis is an efficient technique for multi-pollutants (e.g., organic, inorganic and heavy metals) removal from the landfill leachate. 2017 Taylor & Francis Group, LLC.
Effects of electric potential, NaCl, pH and distance between electrodes on efficiency of electrolysis in landfill leachate treatment
(Taylor and Francis Inc. 325 Chestnut St, Suite 800 Philadelphia PA 19106, 2017) Erabee, I.K.; Ahsan, A.; Jose, B.; Arunkumar, T.; Sathyamurthy, R.; Idrus, S.; Daud, N.N.N.
This study investigated the effects of different parameters on the removal efficiencies of organic and inorganic pollutants in landfill leachate treatment by electrolysis. Different parameters were considered such as the electric potential (e.g., 24, 40 and 60 V), hydraulic retention time (HRT) (e.g., 40, 60, 80, 100 and 120 min), sodium chloride (NaCl) concentration (e.g., 1, 3, 5 and 7%), pH (e.g., 3, 7 and 9), electrodes materials [e.g., aluminum (Al) and iron (Fe)] and distance between electrodes (e.g., 1, 2 and 3 cm). The best operational condition of electrolysis was then recommended. The electric potential of 60 V with HRT of 120 min at 5% of NaCl solution using Al as anode and Fe as cathode (kept at a distance of 3 cm) was the most efficient condition which increased the removal efficiencies of various parameters such as turbidity, salinity, total suspended solids (TSS), total dissolved solids (TDS), biochemical oxygen demand (BOD), chemical oxygen demand (COD) and heavy metals (e.g., Zn and Mn). The higher removal percentages of many parameters, especially COD (94%) and Mn (93%) indicated that the electrolysis is an efficient technique for multi-pollutants (e.g., organic, inorganic and heavy metals) removal from the landfill leachate. © 2017 Taylor & Francis Group, LLC.