Browsing by Author "Chang, F."

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    Hydrogen-Economic Synthesis of Gasoline-like Hydrocarbons by Catalytic Hydrodecarboxylation of the Biomass-derived Angelica Lactone Dimer
    (2017) Chang, F.; Dutta, Saikat; Mascal, M.
    The biomass-derived platform molecule levulinic acid is converted into the angelica lactone dimer (ALD) in high overall yield using simple inorganic catalysts. Hydrodecarboxylation of ALD using a Pd/?-Al2O3 catalyst under moderate hydrogen gas pressure at high temperatures generates branched C8 C9 hydrocarbons in nearly quantitative yield consuming as little as a single equivalent of external hydrogen. These molecules are high-octane drop-in equivalents of isoalkanes used in commercial gasoline. Catalytic hydrodecarboxylation is presented as a highly effective means to reduce hydrogen demand in biomass-to-biofuel conversion technologies. 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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    Hydrogen-Economic Synthesis of Gasoline-like Hydrocarbons by Catalytic Hydrodecarboxylation of the Biomass-derived Angelica Lactone Dimer
    (Wiley Blackwell info@wiley.com, 2017) Chang, F.; Dutta, S.; Mascal, M.
    The biomass-derived platform molecule levulinic acid is converted into the angelica lactone dimer (ALD) in high overall yield using simple inorganic catalysts. Hydrodecarboxylation of ALD using a Pd/?-Al2O3 catalyst under moderate hydrogen gas pressure at high temperatures generates branched C8–C9 hydrocarbons in nearly quantitative yield consuming as little as a single equivalent of external hydrogen. These molecules are high-octane “drop-in” equivalents of isoalkanes used in commercial gasoline. Catalytic hydrodecarboxylation is presented as a highly effective means to reduce hydrogen demand in biomass-to-biofuel conversion technologies. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim